The recent environmental/health and safety regulations placed restrictions of use of hazardous substances on critical manufacturing sectors and consumers’ products. Brass alloys specifically face a challenging issue concerning the elimination of lead (Pb) which has been a critical element affecting both the machinability and overall quality and efficiency of their manufacturing process. The adaptation of novel materials and processing routes in the green economy constitutes a crucial decision for competitive business and industry growth as a worldwide perspective with substantial industrial and social impact. This paper aims to review the emergent innovative and sustainable material solutions in the manufacturing industry, in line with environmental regulations, by highlighting smart alloy design practices and promoting new and innovative approaches for material selection and manufacturing process optimisation. In this review we analyse the processing, structure and machinability aspects of leaded brasses and underline the major guidelines and research methodologies required to overcome this technical challenge and further improve the mechanical properties and machinability of lead-free brass alloys. Various alloying and processing strategies were reviewed together with the most important failure types, as they were extracted from the existing industrial and technological experience, covering more than 20 years of research in this field.

In the current work, a novel medium entropy copper alloy was designed with the aim of avoiding the use of expensive, hazardous or scarce alloying elements and instead employing widely available and cost-effective alternatives. In order to investigate this unknown region of multicomponent alloy compositions, the thermo-physical parameters were calculated and the CALPHAD method was utilized. This led to the design of the Cu₅₀Zn₂₅Al₂₀Sn₅ at. % (Cu_53.45Zn_27.49Al_9.08Sn_9.98 wt. %) alloy with a relatively low density of 6.86 g/cm³ compared with conventional brasses. The designed alloy was manufactured through vacuum induction melting, producing two ingots weighing 1.2 kg each, which were subjected to a series of heat treatments. The microstructural evolution of the alloy in the as-cast and heat-treated conditions was assessed through optical and scanning electron microscopy. The hardness of the as-cast and heat-treated alloy at room temperature was also studied. The alloy was characterized by a multiphase microstructure containing a major Cu-rich (Cu–Zn–Al) matrix reinforced with a secondary Zn-rich (Zn–Cu) phase and pure Sn. In terms of mechanical properties, the developed alloy exhibited high hardness values of roughly 378 HV_0.2 and 499 HV_0.2 in the as-cast and heat-treated conditions, respectively.