Nanoclusters just by adding CO: The most closely packed surfaces of transition metals are usually stable under vacuum, but during catalytic reactions, energetic changes that result from adsorbing molecules could change the surface structure. Eren et al. present an extreme example for carbon monoxide (CO) adsorption on the (111) surface of copper at very low partial pressures. The surface decomposed into small nanoclusters (most containing 3 or 19 atoms). The surface was more reactive than the original and, for example, could dissociate adsorbed water at room temperature. Science , this issue p. 475
Watching graphene grow: The growth of graphene on metal surfaces can be catalyzed by mobile surface metal atoms. Patera et al. used a high-speed scanning tunneling microscope to image the growth of graphene islands on a nickel surface. High temperatures caused carbon to diffuse to the surface, where mobile nickel atoms catalyzed graphene growth on the edges of islands. Molecular dynamics and density functional theory calculations provide mechanistic insights into the reaction steps. Science , this issue p. 1243
17 January 2014 in The Journal of Physical Chemistry Letters