The presented work focused on the development of temperature sensors based on specially formulated carbon nanotube (CNT) and poly(3,4-ethylene dioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) based inks which are deposited directly onto the adhesive polyamide-based taffeta fabric with low-cost office-type inkjet printer. Stable and uniform dispersions of CNT and PEDOT:PSS with Triton X-100 were formulated to be used as temperature sensitive inkjet inks. Three kinds of temperature sensors were fabricated using sensitive materials including CNT ink, PEDOT:PSS ink, and CNT/PEDOT:PSS composite ink. Developed sensors are connected to the measuring devices via silver yarns and silver adhesive paste. Sensors are covered with translucent polyurethane welding tape for packaging and protection. All the sensors exhibit negative temperature coefficient (NTC) behavior and sensitivity of 0.15 %/°C for CNT, 0.41 %/°C for PEDOT:PSS, and 0.31 %/°C for CNT/PEDOT:PSS for temperatures varying from room temperature to 50 °C. CNT/PEDOT:PSS composite ink printed sensor achieved better sensing repeatability and demonstrated higher bending stability with a resistance change of 0.3 % up to 1000 cycles than CNT printed and PEDOT:PSS printed sensors. The softness, lightness, and capability to work on flexible or curved surfaces make the developed CNT/PEDOT:PSS composite ink printed sensor a robust candidate for wearable temperature sensor applications, especially in situations requiring continuous body temperature monitoring while satisfying comfort of the user.
11 January 2021 in Journal of Materials Science: Materials in Electronics
In this study, PEDOT:PSS conductive polymer printed flexible humidity sensor has been designed and fabricated to sense human respiration monitoring. PEDOT:PSS with conductive ink specifically formulated in our study, was printed on polyamide-based taffeta label fabric by an inkjet printing method. The sensitivity of the printed humidity sensor has been tested under different humidity levels inside a humidity chamber. Then, the sensor has been integrated into a face mask in order to evaluate the respiration monitoring of a user who wears the face mask in a real environment. The sensing capability of the wearable sensor and its response against respiration monitoring was evaluated under various breathing conditions such as fast and deep breathing, differentiating nose and mouth breathing. Owing to its flexible structure and printability onto textile, the wearable printed humidity sensor has the potential to be used for healthcare applications particularly for capturing user biomedical data.
We present a flexible pH sensor which leverages the unique properties of reduced graphene oxide/polyaniline (rGO/PANI) composite films through an efficient and scalable hybrid microfabrication approach, wherein the rGO/PANI films are conformally coated on flexible polyethylene terephthalate (PET) substrates via dip-coating and thereafter lithographically patterned into precise arrays of interdigitated electrodes (IDEs), serving both as the pH-active medium and the electrical interface. Upon dip-coating, a thermal reduction process is performed to yield uniform rGO/PANI composite layers on PET substrates, where the PANI content is adjusted to 20% to optimize conductivity and protonation-driven response. Composition optimization is first performed using inkjet-printed silver (Ag) contacts and a conductometric readout mechanism is employed to explore pH-dependent behavior. Subsequently, IDE arrays are defined in the rGO/PANI using photolithography and oxygen-plasma etching, demonstrating clean pattern transfer and dimensional control on flexible substrates. Eliminating separate contact metals in the final design simplifies the stack and reduces cost. A set of IDE geometries is evaluated through I–V measurements in buffers of different pH values, revealing a consistent, monotonic change in electrical characteristics with pH and geometry-tunable response. The present study demonstrated that the most precise pH measurement was achieved with an 80:20 rGO/PANI composition within the pH 2–10 range. These results establish rGO/PANI IDEs as a scalable route to low-cost, miniaturized, and mechanically compliant pH sensors for field and in-line monitoring applications.