A CMOS cross‐coupled RF rectifier that improves power conversion efficiency (PCE) with low reverse leakage current for energy harvesting wireless sensors is proposed. In this Letter, the authors propose a CMOS cross‐coupled differential RF rectifier that uses a thick‐oxide MOSFET as a rectifying device to improve PCE by reducing reverse leakage current. The proposed rectifier is designed for UHF band application using 0.18 µm CMOS technology. Proposed rectifier achieves a peak PCE of 75.2% and sensitivity of − 17 dBm for 1 V output voltage. Peak PCE is improved by 8.8% compared to the conventional rectifier.
Iridescent color-shift pigments have been used in some industrial applications, e.g., for cosmetics and packaging. To achieve environmental-friendly and lasting color, thin-film interference is used to generate structural color. By maximizing the refractive index (RI) difference between the thin films (i.e., using an ultralow RI film), super-iridescent structural color can be produced. While the lowest refractive index of a naturally occurring solid dielectric is close to 1.37 (i.e., MgF2), we synthesized highly porous dielectric SiO2 aerogel to achieve ultralow-RI (n ~ 1.06) and demonstrated a high-refractive index/low-refractive index/absorber (HLA) trilayer structural color. The achieved structural color is highly iridescent and capable of tracing a near-closed loop in CIE color space. By tuning the refractive index, thickness, and geometry of the aerogel layer, we control the reflection dip’s shape, therefore producing a wide range of vivid and iridescent colors.
An enhancement of the local electric field at the metal/dielectric interface of hybrid materials due to the localized surface plasmon resonance (LSPR) phenomenon plays a particularly important role in versatile research fields resulting in a distinct modification of the electrical, as well as optical, properties of the hybrid material. In this paper, we succeeded in visually confirming the LSPR phenomenon in the crystalline tris(8-hydroxyquinoline) aluminum (Alq3) micro-rod (MR) hybridized with silver (Ag) nanowire (NW) in the form of photoluminescence (PL) characteristics. Crystalline Alq3 MRs were prepared by a self-assembly method under the mixed solution of protic and aprotic polar solvents, which could be easily applied to fabricate hybrid Alq3/Ag structures. The hybridization between the crystalline Alq3 MRs and Ag NWs was confirmed by the component analysis of the selected area electronic diffraction attached to high-resolution transmission electron microscope. Nanoscale and solid state PL experiments on the hybrid Alq3/Ag structures using a lab-made laser confocal microscope exhibited a distinct enhancement of the PL intensity (approximately 26-fold), which also supported the LSPR effects between crystalline Alq3 MRs and Ag NWs.
We experimentally demonstrate the direct visualization of ultraviolet (UV) light using flexible polymer composite films consisting of crystalline organic tris-(8-hydroxyquinoline) aluminum (Alq3) micro-rods and polydimethylsiloxane (PDMS). The representative organic mono-molecule Alq3, which is a core material of organic light-emitting diodes, was used to detect light in the invisible UV region and visualize photoluminescence (PL). Alq3 shows absorption in the UV region and light-emitting characteristics in the green region, making it an optimal material for UV visualization because of its large Stokes transition. Crystalline Alq3 micro-rods were fabricated in a deionized water solution through a sequential process of reprecipitation and self-assembly. Highly bright photoluminescence was observed on the highly crystalline Alq3 micro-rods under UV light excitation, indicating that the crystalline structures of Alq3 molecules affect the visible emission decay of excitons. The Alq3 micro-rods were manufactured as flexible polymer composite films using a PDMS solution to observe UV photodetector characteristics according to UV intensity, and it was confirmed that the intensity of the fine UV light reaching the earth’s surface can be visualized by making use of this UV photodetector.