The productivity of boreal forests is considered to be limited by low nitrogen (N) availability. Increased atmospheric N deposition has altered the functioning and N cycling of these N-sensitive ecosystems by increasing the availability of reactive nitrogen. The most important components of N pools and fluxes were measured in a boreal Scots pine stand in Hyytiälä, Southern Finland. The measurements at the site allowed direct estimations of nutrient pools in the soil and biomass, inputs from the atmosphere and outputs as drainage flow and gaseous losses from two micro-catchments. N was accumulating in the system, mainly in woody biomass, at a rate of 7 kg N ha⁻¹ yr⁻¹. Nitrogen input as atmospheric deposition was 7.4 kg N ha⁻¹ yr⁻¹. Dry deposition and organic N in wet deposition contributed over half of the inputs in deposition. Total outputs were 0.4 kg N ha⁻¹ yr⁻¹, the most important outputs being N₂O emission to the atmosphere and organic N flux in drainage flow. Nitrogen uptake and retranslocation were equally important sources of N for plant growth. Most of the assimilated N originated from decomposition of organic matter, and the fraction of N that could originate directly from deposition was about 30%. In conclusion, atmospheric N deposition fertilizes the site considerably, but there are no signs of N saturation. Further research is needed to estimate soil N₂ fluxes (emission and fixation), which may amount up to several kg N ha⁻¹ yr⁻¹.

Climatic effects of newly-formed atmospheric secondary aerosol particles are to a large extent determined by their condensational growth rates. However, all the vapours condensing on atmospheric nanoparticles and growing them to climatically relevant sizes are not identified yet and the effects of particle phase processes on particle growth rates are poorly known. Besides sulfuric acid, organic compounds are known to contribute significantly to atmospheric nanoparticle growth. In this study a particle growth model MABNAG (Model for Acid-Base chemistry in NAnoparticle Growth) was developed to study the effect of salt formation on nanoparticle growth, which has been proposed as a potential mechanism lowering the equilibrium vapour pressures of organic compounds through dissociation in the particle phase and thus preventing their evaporation. MABNAG is a model for monodisperse aqueous particles and it couples dynamics of condensation to particle phase chemistry. Non-zero equilibrium vapour pressures, with both size and composition dependence, are considered for condensation. The model was applied for atmospherically relevant systems with sulfuric acid, one organic acid, ammonia, one amine and water in the gas phase allowed to condense on 3–20 nm particles. The effect of dissociation of the organic acid was found to be small under ambient conditions typical for a boreal forest site, but considerable for base-rich environments (gas phase concentrations of about 10¹⁰ cm⁻³ for the sum of the bases). The contribution of the bases to particle mass decreased as particle size increased, except at very high gas phase concentrations of the bases. The relative importance of amine versus ammonia did not change significantly as a function of particle size. While our results give a reasonable first estimate on the maximum contribution of salt formation to nanoparticle growth, further studies on, e.g. the thermodynamic properties of the atmospheric organics, concentrations of low-volatility organics and amines, along with studies investigating the applicability of thermodynamics for the smallest nanoparticles are needed to truly understand the acid-base chemistry of atmospheric nanoparticles.

Vegetation is known to have strong influence on evapotranspiration (ET), a major component of terrestrial water balance. Yet hydrological models often describe ET by methods unable to include the variability of vegetation characteristics in their predictions. To take advantage of the increasing availability of high-resolution open GIS data on land use, vegetation and soil characteristics in the boreal zone, a modular, spatially distributed model for predicting ET and other hydrological processes from grid cell to catchment level is presented and validated. An improved approach to upscale stomatal conductance to canopy scale using information on plant type (conifer/deciduous) and stand leaf-area index (LAI) is proposed by coupling a common leaf-scale stomatal conductance model with a simple canopy radiation transfer scheme. Further, a generic parametrization for vegetation-related hydrological processes for Nordic boreal forests is derived based on literature and data from a boreal FluxNet site. With the generic parametrization, the model was shown to reproduce daily ET measured using an eddy-covariance technique well at 10 conifer-dominated Nordic forests whose LAI ranged from 0.2 to 6.8 m² m⁻². Topography, soil and vegetation properties at 21 small boreal headwater catchments in Finland were derived from open GIS data at 16 m × 16 m grid size to upscale water balance from stand to catchment level. The predictions of annual ET and specific discharge were successful in all catchments, located from 60 to 68^∘ N, and daily discharge was also reasonably well predicted by calibrating only one parameter against discharge measurements. The role of vegetation heterogeneity in soil moisture and partitioning of ET was demonstrated. The proposed framework can support, for example, forest trafficability forecasting and predicting impacts of climate change and forest management on stand and catchment water balance. With appropriate parametrization it can be generalized outside the boreal coniferous forests.