In this twenty-first century, energy shortages have become a global issue as energy demand is growing at an astounding rate while the energy supply from fossil fuels is depleting. Thus, the urge to develop sustainable renewable energy to replace fossil fuels is significant to prevent energy shortages. Solar energy is the most promising, accessible, renewable, clean, and sustainable substitute for fossil fuels. Third-generation (3G) emerging solar cell technologies have been popular in the research field as there are many possibilities to be explored. Among the 3G solar cell technologies, perovskite solar cells (PSCs) are the most rapidly developing technology, making them suitable for generating electricity efficiently with low production costs. However, the toxicity of Pb in organic–inorganic metal halide PSCs has inherent shortcomings, which will lead to environmental contamination and public health problems. Therefore, developing a lead-free perovskite solar cell is necessary to ensure human health and a pollution-free environment. This review paper summarized numerous types of Sn-based perovskites with important achievements in experimental-based studies to date.
Graphene is a single atomic plane of sp2-bound carbon that has attracted considerable interest in various technologies. On the basis of its unique physical, mechanical, and chemical properties, graphene is a potentially strong candidate as a lubricant additive in its liquid-based form to reduce friction and protect surfaces from degrading. Furthermore, graphene on wear performance acts as a heat dissipation source for liquid lubricants. This review explores and addresses the fundamental mechanisms illuminating the exceptional tribological behaviours of graphene family materials and their limitations. Although graphene additives were reported to improve friction coefficients and wear properties, several challenges remain a hindrance, such as production costs, dispersion stability, and lack of information regarding graphene optimisation. Thus, this review can provide a standard methodological framework for graphene additives in improving tribological performance. Moreover, this review provides an up-to-date review of current tribological experiments based on ultrafine particles incorporated with graphene as an additive for lubricating liquids.
Due to their remarkable electrical and light absorption characteristics, hybrid organic-inorganic perovskites have recently gained popularity in several applications such as optoelectronics, lasers, and light-emitting diodes. Through this, there has recently been an increase in the use of halide perovskites (HPs) in resistive switching (RS) devices. However, lead-based (Pb-based) perovskites are notorious for being unstable and harmful to the environment. As a result, lead-free (Pb-free) perovskite alternatives are being investigated in achieving the long-term and sustainable use of RS devices. This work describes the characteristics of Pb-based and Pb-free perovskite RS devices. It also presents the recent advancements of HP RS devices, including the selection strategies of perovskite structures. In terms of resistive qualities, the directions of both HPs appear to be identical. Following that, the possible impact of switching from Pb-based to Pb-free HPs is examined to determine the requirement in RS devices. Finally, this work discusses the opportunities and challenges of HP RS devices in creating a stable, efficient, and sustainable memory storage technology.