Amorphous materials feature unique structures and physicochemical properties, resulting in their synthesis and applications becoming a dynamic and fascinating new research direction. The high specific surface area, abundant active sites, and good electron transport properties endow amorphous materials with excellent electrocatalytic properties, thus appealing to increasing attention. Based on this, the summary of the current research status of amorphous catalysts in the field of electrocatalysis is urgent and important. In this review, the research progress of amorphous catalysts in electrocatalysis is systematically introduced, focusing on the classification, synthesis methods, modification strategies, characterizations, and electrocatalytic application (including hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, carbon dioxide reduction reaction, and nitrogen reduction reaction). Finally, this review proposes the prospects and challenges for the future development of high-active and high-selectivity amorphous electrocatalysts.