The purpose of this work is to study Rossby wave parameters in total ozone over the Arctic in 2000–2021. We consider the averages in the January–March period, when stratospheric trace gases (including ozone) in sudden stratospheric warming events are strongly disturbed by planetary waves. To characterize the wave parameters, we analyzed ozone data at the latitudes of 50°N (the sub-vortex area), 60°N (the polar vortex edge) and 70°N (inner region of the polar vortex). Total ozone column (TOC) measurements over a 22-year time interval were used from the Total Ozone Mapping Spectrometer/Earth Probe and Ozone Mapping Instrument/Aura satellite observations. The TOC zonal distribution and variations in the Fourier spectral components with zonal wave numbers m = 1–5 are presented. The daily and interannual variations in TOC, amplitudes and phases of the spectral wave components, as well as linear trends in the amplitudes of the dominant quasi-stationary wave 1 (QSW1), are discussed. The positive TOC peaks inside the vortex in 2010 and 2018 alternate with negative ones in 2011 and 2020. The extremely low TOC at 70°N in 2020 corresponds to severe depletion of stratospheric ozone over the Arctic in strong vortex conditions due to anomalously low planetary wave activity and a high positive phase of the Arctic Oscillation. Interannual TOC variations in the sub-vortex region at 50°N are accompanied by a negative trend of −4.8 Dobson Units per decade in the QSW1 amplitude, statistically significant at 90% confidence level, while the trend is statistically insignificant in the vortex edge region and inside the vortex due to the increased variability in TOC and QSW1. The processes associated with quasi-circumpolar migration and quasi-stationary oscillation of the wave-1 phase depending on the polar vortex strength in 2020 and 2021 are discussed.

The aim of this work is to study the zonally asymmetric stratopause that occurred in the Arctic winter of 2019/2020, when the polar vortex was particularly strong and there was no sudden stratospheric warming. Aura Microwave Limb Sounder temperature data were used to analyze the evolution of the stratopause with a particular focus on its zonally asymmetric wave 1 pattern. There was a rapid descent of the stratopause height below 50 km in the anticyclone region in mid-December 2019. The descended stratopause persisted until mid-January 2020 and was accompanied by a slow descent of the higher stratopause in the vortex region. The results show that the stratopause in this event was inclined and lowered from the mesosphere in the polar vortex to the stratosphere in the anticyclone. It was found that the vertical amplification of wave 1 between 50 km and 60 km closely coincides in time with the rapid stratopause descent in the anticyclone. Overall, the behavior contrasts with the situation during sudden stratospheric warmings when the stratopause reforms at higher altitudes following wave amplification events. We link the mechanism responsible for coupling between the vertical wave 1 amplification and this form of zonally asymmetric stratopause descent to the unusual disruption of the quasi-biennial oscillation that occurred in late 2019.

Extraordinarily high aerosol contamination was observed in the atmosphere over the city of Kyiv, Ukraine, during the March–April 2020 period. The source of contamination was the large grass and forest fires in the northern part of Ukraine and the Kyiv region. The level of PM2.5 load was investigated using newly established AirVisual sensor mini-networks in five areas of the city. The aerosol data from the Kyiv AERONET sun-photometer site were analyzed for that period. Aerosol optical depth, Ångström exponent, and the aerosol particles properties (particle size distribution, single-scattering albedo, and complex refractive index) were analyzed using AERONET sun-photometer observations. The smoke particles observed at Kyiv site during the fires in general correspond to aerosol with optical properties of biomass burning aerosol. The variability of the optical properties and chemical composition indicates that the aerosol particles in the smoke plumes over Kyiv city were produced by different burning materials and phases of vegetation fires at different times. The case of enormous PM2.5 aerosol contamination in the Kyiv city reveals the need to implement strong measures for forest fire control and prevention in the Kyiv region, especially in its northwest part, where radioactive contamination from the Chernobyl disaster is still significant.

The purpose of this work is to study quasi-stationary wave structure in the mid-latitude stratosphere and mesosphere (40–50°N) and its role in the formation of the annual ozone cycle. Geopotential height and ozone from Aura MLS data are used and winter climatology for January–February 2011–2020 is considered. The 10-degree longitude segment centered on Longfengshan Brewer station (44.73°N, 127.60°E), China, is examined in detail. The station is located in the region of the Aleutian Low associated with the quasi-stationary zonal maximum of total ozone. Annual and semi-annual oscillations in ozone using units of ozone volume mixing ratio and concentration, as well as changes in ozone peak altitude and in time series of ozone at individual pressure levels between 316 hPa (9 km) and 0.001 hPa (96 km) were compared. The ozone maximum in the vertical profile is higher in volume mixing ratio (VMR) values than in concentration by about 15 km (5 km) in the stratosphere (mesosphere), consistent with some previous studies. We found that the properties of the annual cycle are better resolved in the altitude range of the main ozone maximum: middle–upper stratosphere in VMR and lower stratosphere in concentration. Both approaches reveal annual and semi-annual changes in the ozone peak altitudes in a range of 4–6 km during the year. In the lower-stratospheric ozone of the Longfengshan domain, an earlier development of the annual cycle takes place with a maximum in February and a minimum in August compared to spring and autumn, respectively, in zonal means. This is presumably due to the higher rate of dynamical ozone accumulation in the region of the quasi-stationary zonal ozone maximum. The “no-annual-cycle” transition layers are found in the stratosphere and mesosphere. These layers with undisturbed ozone volume mixing ratio are of interest for more detailed future study.

Extraordinary high aerosol contamination observed in the atmosphere over Kyiv city, Ukraine, during the March – April 2020 period. The source of contamination was the large grass and forest fires in the northern part of Ukraine and the Kyiv region. The level of PM2.5 load investigated using newly established AirVisual sensors mini-network in five areas of the city. The aerosol data from the Kyiv AERONET sun-photometer site analyzed for that period. Aerosol optical depth, Angstrom exponent, and the aerosol particles properties (particles size distribution, single-scattering albedo, and complex refractive index) were analyzed using AERONET sun-photometer observations. The smoke particles observed at Kyiv site during the fires in general correspond to aerosol with optical properties of biomass burning particles. The variability of the optical properties and chemical composition indicates that the aerosol particles in the smoke plumes over Kyiv were produced by different burning material and phases of vegetation fires at different time. The case of enormous PM2.5 aerosol contamination in Kyiv city reveals the need to accept strong measures for forest fire control and prevention in Kyiv region, especially in the north-west region where radioactive contamination from Chornobyl disaster is still significant.

The aim of this work is to study the zonally asymmetric stratopause that occurred in the Arctic winter of 2019/2020, when the polar vortex was particularly strong and there was no sudden stratospheric warming. Aura Microwave Limb Sounder temperature data were used to analyze the evolution of the stratopause with a particular focus on its zonally asymmetric wave 1 pattern. There was a rapid descent of the stratopause height below 50 km in the anticyclone region in mid-December 2019. The descended stratopause persisted until mid-January 2020 and was accompanied by a slow descent of the higher stratopause in the vortex region. The results show that the stratopause in this event was inclined and lowered from the mesosphere in the polar vortex to the stratosphere in the anticyclone. It was found that the vertical amplification of wave 1 between 50 km and 60 km closely coincides in time with the rapid stratopause descent in the anticyclone. Overall, the behavior contrasts with the situation during sudden stratospheric warmings when the stratopause reforms at higher altitudes following wave amplification events. We link the mechanism responsible for coupling between the vertical wave 1 amplification and this form of zonally asymmetric stratopause descent to the unusual disruption of the quasi-biennial oscillation that occurred in late 2019.