High entropy alloy attracts great attention for its high thermal stability and corrosion resistance. A CoCrFeNiMn high-entropy alloy coating was deposited on grey cast iron through plasma transfer arc cladding. It formed fine acicular martensite near the grey cast iron, with columnar grains perpendicular to the interface between the grey cast iron substrate and the cladding layer as well as dendrite in the middle part of the coatings. Simple FCC solid solutions present in the coatings which were similar to the powder’s structure. The coating had a microhardness of 300 ± 21.5 HV_0.2 when the cladding current was 80 A for the solid solution strengthening. The HEA coating had the highest corrosion potential of −0.253 V when the plasma current was 60 A, which was much higher than the grey cast iron’s corrosion potential of −0.708 V. Meanwhile, the coating had a much lower corrosion current density of 9.075 × 10⁻⁷ mA/cm² than the grey cast iron’s 2.4825 × 10⁻⁶ mA/cm², which reflected that the CoCrFeNiMn HEA coating had much better corrosion resistance and lower corrosion rate than the grey cast iron for single FCC solid solution phase and a relatively higher concentration of Cr in the grain boundaries than in the grains and this could lead to corrosion protection effects.

Gd and Yb elements have high chemical stability, which can stabilize the solid solution in ZrO₂. Gd₂O₃ and Yb₂O₃ have high melting points, and good oxidation resistance in extreme environments, stable chemical properties. Therefore, Gd₂O₃ and Yb₂O₃ were added to ZrO₂ to stabilize oxides, improve the high temperature stability, and effectively decrease the thermal conductivity at high temperature. In this work, 5 wt% Yb₂O₃ and 5 wt%, 10 wt%, 15 wt% Gd₂O₃ were doped into 8 wt% Y₂O₃ stabilized ZrO₂ (8YSZ) powders as thermal barrier coating materials, and sintered at 1650 °C for 6 h, 12 h, 24 h. The effects of Gd₂O₃ addition on the microstructure, density, thermal conductivity, hardness, and fracture toughness of Gd₂O₃-Yb₂O₃-Y₂O₃-ZrO₂ (GYYZO) bulk composite ceramics were investigated. It was found that the densification of the 8YSZ bulk and GYYZO bulk with 15 wt% Gd₂O₃ reached 96.89% and 96.22% sintered at 1650 °C for 24 h. With the increase of Gd₂O₃ addition, the hardness, elastic modulus and fracture toughness of the GYYZO bulk increased and the thermal conductivity and thermal expansion coefficient of the GYYZO bulk decreased. GYYZO bulk with 15 wt% Gd₂O₃ sintered at 1650 °C for 24h had the highest hardness, elastic modulus and fracture toughness of 15.61 GPa, 306.88 GPa, 7.822 MPa·m^0.5, and the lowest thermal conductivity and thermal expansion coefficient of 1.04 W/(m·k) and 7.89 × 10⁻⁶/°C at 1100 °C, respectively. The addition of Gd₂O₃ into YSZ could not only effectively reduce the thermal conductivity but also improve the mechanical properties, which would improve the thermal barrier coatings’ performances further.

High-entropy alloys receive more attention for high strength, good ductility as well as good wear resistance. In this work, CoCrFeNiMn high-entropy alloy (HEA) coatings were deposited on compacted graphite iron through plasma transfer arc at different currents. The microstructure and wear properties of the CoCrFeNiMn HEA coatings were investigated. The coatings are composed of single phase with FCC structure. The CoCrFeNiMn HEA coating had the highest microhardness of 394 ± 21.6 HV_0.2 and the lowest wear mass loss when the plasma current was 65 A. All of the HEA coatings had higher friction coefficients than that of the substrate. There were adhesive, abrasive and oxidation wear forms in the HEA coatings with the wear couple of N80 alloy. The HEA coating presented higher friction coefficient and better wear resistance than compacted graphite iron.

The oxidation mechanism of vermicular graphite cast iron was studied. The oxidation reaction starts from graphites and diffused slowly. Graphites in vermicular graphite are interconnected, coral-like clusters, providing the main oxidation core and channel. The worm-like graphites on the surface are mostly oxidized and form oxide affected zones. The oxide films are composed of a loose oxide layer with the phases of Fe₃O₄, Fe₂O₃, and FeO, and a dense passivation layer with FeO and Fe₂SiO₄. After oxidation, pearlites in the vermicular graphite cast iron are decomposed into ferrite and cementite at high temperatures.

Plasma transfer arc cladding technology has been widely utilized in surface engineering, repairing and remanufacturing. In the present work, multiple cladded thick claddings were prepared on compacted graphite cast iron (CGI) substrates with iron-based powders through plasma transfer arc cladding technology using different plasma arc currents to improve the surface wear resistance. The coatings’ phase and microstructure were analysed through XRD, SEM and EDS. The coatings’ microhardness and wear resistance were characterized. There were pearlite, graphite, austenite and secondary carbides in the iron-based alloy coatings. Due to the heat influence during the multiple cladding process, a spheroidal graphite transition zone appeared between the substrate and the coating. The microhardness of the claddings varied from 363 to 402 HV as the plasma arc current was changed from 45 to 60 A. With the increase of plasma arc current, the cladding’s microhardness increased. The iron-based coating’s minimum friction coefficient and wear mass loss were about 0.48 and 4.2 mg, respectively, when the plasma arc current was 60 A, which are lower values than those of the compacted graphite iron substrate with the friction coefficient and wear mass loss of 0.55 and 8.2 mg. Compared with the substrate, the iron-based alloy claddings achieved the effect of reducing friction and wear resistance simultaneously, which resulted from the self-lubricating effect of graphite and high wear-resistance of carbides in the claddings. The iron-based coatings had a similar abrasive wear mechanism to the CGI, which should be helpful to repair or remanufacture CGI workpieces.

In this work, Gd₂O₃ bulks were sintered at temperatures ranging from 1400 °C to 1600 °C for times from 6 h to 24 h, and their microstructure and properties were studied for a wider application of materials in thermal barrier coatings. The densification of the Gd₂O₃ bulk reached 96.16% when it was sintered at 1600 °C for 24 h. The elastic modulus, hardness, fracture toughness and thermal conductivity of the bulks all increased with the rise in sintering temperature and extension of sintering time, while the coefficient of thermal expansion decreased. When the Gd₂O₃ bulk was sintered at 1600 °C for 24 h, it had the greatest elastic modulus, hardness, fracture toughness and thermal conductivity of 201.15 GPa, 9.13 GPa, 15.03 MPa·m^0.5 and 2.75 W/(m·k) (at 1100 °C), respectively, as well as the smallest thermal expansion coefficients of 6.69 × 10⁻⁶/°C (at 1100 °C).