Outside the wide range of potential benefits, the use of nanomaterials can endanger human health, mostly through skin contact and the risk of inhalation. This article presents the results of harmonized measurements with contextual information on the emission of nanoparticles during the manufacturing and application of nanotechnology products. The purpose of the research was to investigate the actual levels of exposure to nano-objects in real working conditions in chosen Polish companies. Measurements were carried out in various workplaces: during silver nanoparticle synthesis, production of thin nanocarbon layers, 3D-printing with the use of a nanohydroxyapatite-polymer composite and the production of special seals from thin glass foils. Research was conducted on the basis of task-based measurements and offline microscopic analysis. Real-time particle DiSCmini counters were used to determine the nano-object concentration during different processes and events: samplers for collecting air dust, and a scanning electron microscope to confirm the presence of nanoparticles emitted from selected sources. Average particle sizes obtained with analysis of microscopic images were as follows: 46.7 ± 13.4 nm, 19.8 ± 4.8 nm, 22.4 ± 7.6 nm, 49.2 ± 26.3 nm respectively for workplaces. The concentration during significant events was referred to the background particle level. During one of the repeated processes, an unexpected and extremely high nanoparticle emission was recorded, which, in the long run, could cause a health hazard to workers. The studies have shown the importance of collective protective measures, revealed unexpected sources of accidentally generated nanoparticles and allowed to obtain knowledge about levels of exposure to nanoparticles during the various processes.
1 January 2022 in Aerosol and Air Quality Research
The dynamics of filtration efficiency and pressure drop during the simultaneous filtration of soot and oil aerosols on single- and multi-layer filters were investigated, and the determined filtration efficiency was compared with the theoretical efficiency obtained via the classical filtration theory. Additionally, the influence of liquid-phase aerosols on the morphology of the formed deposits was investigated. It was concluded that the addition of oil aerosols decreased the filtration efficiency and lowered the pressure drop increase rate for multi-layer filters. Additionally, for the filtration of aerosols containing soot and high oil concentrations, once maximum filtration efficiency was reached, an efficiency decrease occurred. The system imperfection factor was proposed as a mean to predict the efficiency of multi-layer filters. The modified version of the single fibre efficiency method was used to calculate filter mass change with reasonable accuracy.
The pressure drop dynamics during the filtration of three-component mixture aerosols are investigated and compared with two and single-component aerosols. The main area of interest is the effect of the addition of a small quantity of liquid (oil) and solid (soot) particles during the filtration of aerosol containing water mist. In addition, calculations of the change in filter mass during oil aerosol filtration have been carried out and compared with the experimental results. The new, improved filtration efficiency model takes into account a better coefficient fitting in the filtration mechanism equations. The limitations in the change in fibre diameter and packing density resulting from the filter loading have been implemented in the model. Additionally, the calculation model employs the fibre size distribution representation via multiple average fibre diameters. The changes in fibre diameter are dependent on each fibre’s calculated filtration efficiency. The improved filtration model has been utilised to predict the mass change of the filters during the filtration of pure and mixture aerosols. The pressure drop calculation model based on changes in filter mass has been formulated. The model is then utilised to calculate pressure drop changes resulting from the filtration of the oil aerosol and water and oil mixture aerosol.
1 April 2020 in Separation and Purification Technology
This paper discusses the potential of additive printing, the risks it poses to users’ health (including 3D printer operators) and the effects of chemical substances released during the printing based on the available in vitro and in vivo studies. It was shown that substances emitted during...
In 2019, the European Committee for Standardization (CEN) initiated work on the preparation of a strategy for air quality monitoring at workplaces. The aim was to determine the concentrations of nano-objects and their aggregates and agglomerates (NOAA) by means of direct measurements using low-cost sensors. There is a growing need for low-cost devices that can continuously monitor the concentrations of nanoparticles, and that can be installed where nanoparticles are used or created spontaneously. In search of such a device, in this study, a smoke detector with an ionization sensor was tested. The aim of the research was to investigate the response of the analog output signal with respect to changes in environmental parameters such as the relative humidity of air. The research was conducted in controlled laboratory conditions, and the results confirmed that an ionization detector could be used to measure the concentrations of nanoaerosols. The modified smoke detector detected soot particles smaller than 100 nm. The linear regression line was calculated for the relative humidity dataset and had a slope coefficient of −1.214 × 10−4; thus, the value of the output signal was constant during the experiment. The dependence on air temperature was approximated by a second-degree curve, with a slope coefficient of −8.113 × 10−2. Air humidity affected aerosol concentrations, which may be related to surface modification of nanoparticles.