Pharmaceuticals put the environment at high risk when found in products of wastewater treatment plants, hence need to be removed efficiently. This study quantified selected pharmaceutically active compounds (PhACs) (diclofenac, aspirin, paracetamol, and ibuprofen) in wastewater and evaluated its removal efficiency from wastewater treatment plant (WWTP). Samples were taken from the WWTP of the Sewerage Systems Ghana Limited (SSGL) for 18 consecutive days. Both effluents and influents were tested in the laboratory to determine the concentrations of the various pharmaceutical products. The results reveal diclofenac as the PhAC with the highest concentration in the influent with an average of 121.31 μg/ml. Paracetamol recorded an average of 65.54 μg/ml, then ibuprofen with an average of 19.54 μg/ml. Aspirin was the PhAC with the lowest concentration in the influent with an average of 0.27 μg/ml. Further assessment was also done on the trickling filter (biological filter) which is part of the process plant at the secondary stage to assess how the trickling filter aids in the removal of these selected pharmaceuticals.

This research aimed to evaluate the comparative biogas yields of waste (peels) of selected fibrous materials from the West African region: cassava, plantain, a mixture of cassava, plantain and yam. Three models: The Boyle model, the Modified Boyle’s model, and the Buswell and Müller’s model were used to determine the theoretical maximum biomethane potential (TBMP), while the Hohenheim Biogas Yield test (D-HBT) was used to undertake a batch test of anaerobic digestion. The samples were co-digested with digested sewage sludge (DSS) for 39 days, with an operating temperature of 37 ± 0.5 °C. The study draws comparisons between the TBMPs and the experimental results, the experimental results of the different substrates, and the experimental results and figures reported in the literature. From the experimental results, plantain peels had the highest biogas yield (468 ± 72 mL/g _oTS), followed by a mixture of yam, cassava and plantain peels (362 ± 31 mL/g _oTS) and cassava peels obtained the least biogas yield (218 ± 19 mL/g _oTS). TBMPS of 204.04, 209.03 and 217.45 CH₄ mL/g _oTS were obtained for plantain peels, a mixture of yam, cassava and plantain peels and cassava peels, respectively, evaluated using Boyle’s model. For all the samples, the TBMPS (205.56, 209.03 and 218.45 CH_{4 mL}/g _oTS, respectively) obtained using the Buswell and Mueller model were slightly higher than those obtained by both the Boyle and the modified Boyle’s model (163.23, 167.22 and 174.76 CH₄ mL/g _oTS, respectively). While the study result is sufficient to imply that generating biogas from fibrous waste materials in its mixture form is a valuable approach, it is not sufficient to conclude that the use of these waste materials in its naturally occurring mixture form has a technical added advantage in co-digestion over their individual potential. However, future studies could explore this possibility with different fractions of the mixture with a view to optimising generation. The study finds that theoretically modelling the biogas potential of fibrous materials is a good method for biogas evaluation despite having overestimation tendencies, as this challenge could be corrected by applying factors that result in these tendencies, biodegradability indices. The data can, therefore, find use in fibrous waste treatment and waste-to-energy technologies, especially in Africa. This application will not be negatively affected by whether single waste streams are used or their mixture.

Anaerobic digestion has the potential to convert organic waste materials into valuable energy. At the same time, using press water from biomass materials for energy generation while taking advantage of the resulting cake for other purposes is an emerging approach. Therefore, this study aimed to investigate the residual potential expected from a typical biogas feedstock after it has been mechanically separated into liquid and solid phases. Hence, in this study, the rumen contents of ruminants (cow, goat, and sheep) and their proportionate ratios were obtained from an abattoir in Ghana. Resource characterization of the waste samples was carried out in the central laboratory of the HFR, Germany. Anaerobic batch tests for biogas (biomethane) yield determination were set up using the Hohenheim Biogas Yield Test (HBT). The inoculum used was obtained from an inoculum production unit at the Hohenheim University biogas laboratory. The trial involved two different forms of the sample: mixture of rumen contents, press water, and inoculum, each in four (4) replicates. The trial was carried out at a mesophilic temperature of 37 °C. Results obtained over a seventy (70) day period were transformed into biogas yields. Overall, the results show that the current contents are suitable for biogas generation as an option as opposed to the current form of disposal at a refuse dump. However, using these mixtures in their original forms is more technically viable than using press water without further treatment.