The influences of glucose and amino acid (L-cysteine) on the degradation of pure magnesium have been investigated using SEM, XRD, Fourier transformed infrared (FTIR), X-ray photoelectron spectroscopy (XPS), polarization and electrochemical impedance spectroscopy and immersion tests. The results demonstrate that both amino acid and glucose inhibit the corrosion of pure magnesium in saline solution, whereas the presence of both amino acid and glucose accelerates the corrosion rate of pure magnesium. This may be due to the formation of -C=N- bonding (a functional group of Schiff bases) between amino acid and glucose, which restricts the formation of the protective Mg(OH)2 precipitates.
28 April 2009 in Metallurgical and Materials Transactions A
A nano-ZrO2 modified coating system was prepared by incorporation of nano-ZrO2 concentrates into phenolic-epoxy resin. The corrosion performance of the coatings was evaluated in hot mixed acid solution, using electrochemical methods combined with surface characterization, and the effects of nano-ZrO2 content were specially focused on. The results showed that 1% and 3% nano-ZrO2 addition enhanced the corrosion resistance of the coatings, while 5% nano-ZrO2 addition declined it. The coating with 3% nano-ZrO2 presented the minimum amount of species diffusion, the lowest average roughness (5.94 nm), and the highest C/O ratio (4.55) and coating resistance, and it demonstrated the best corrosion performance among the coating specimens.
11 July 2019 in Acta Metallurgica Sinica (English Letters)