Thollwana Makhetha

Dr. Thollwana Makhetha

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Research Focus & Metrics

Academic Career Length

12Years (2015-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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29 March 2024 in ACS Omega
Verified
Journal Article
Open access
NSNjabulo Sondezi
Njabulo Sondezi
ZNZikhona Njengele-Tetyana
Zikhona Njengele-Tetyana
KMKgabo Phillemon Matabola
Kgabo Phillemon Matabola
TMThollwana Makhetha
Thollwana Makhetha
This study reports on the antibacterial efficacy of both the TiO2 and TiO2/Cu nanoparticles prepared through the sol-gel method. The materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and Brunauer-Emmett-Teller (BET) analysis. The SEM and TEM showed the spherical morphology of the nanoparticles, while EDX and XPS confirmed the incorporation of Cu into the TiO2 nanoparticles. The XRD confirmed the formation of the tetragonal anatase phase of TiO2/Cu while the FTIR revealed the functional groups linked to the doped TiO2 nanoparticles. The thermal stability of TiO2/Cu was found to be lower than pure TiO2. Moreover, TiO2 and the doped TiO2 nanoparticles were notably effective against Bacillus subtilis(B. subtilis) andEscherichia coli(E. coli); however, the addition of Cu to TiO2 did not have any effect on the antibacterial activity probably due to the lower weight content in the composites. Interestingly, the antibacterial efficiency was determined to be 90 and 80% against B. subtilis and E. coli, respectively.


17 April 2022 in Membranes
Verified
Journal Article
Open access
PDF file
EMElizabeth Gaobodiwe Masibi
Elizabeth Gaobodiwe Masibi
TMThollwana Makhetha
Thollwana Makhetha
Richard MoutloaliRichard Moutloali
Richard Moutloali
A series of Zeolitic imidazole framework-8 (ZIF-8) clusters supported on graphene oxide (ZIF-8@GO) nanocomposites were prepared by varying the ratios of ZIF-8 to GO. The resultant nanocomposites were characterized using various techniques, such as Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), thermogravimetric analysis (TGA), Fourier Transform Infrared (FTIR) and Raman spectroscopy. These nanocomposites were incorporated into the thin film layer during interfacial polymerisation process of m-phenylenediamine (aqueous phase which contained the dispersed nanocomposites) and trimesoyl chloride (TMC, organic phase) at room temperature onto polyethersulfone (PES) ultrafiltration (UF) support membrane. The membrane surface morphology, cross section and surface roughness were characterized using SEM and AFM, respectively. Compared to the baseline membranes, the thin film nanofiltration (TFN) membranes exhibited improved pure water flux (from 1.66 up to 7.9 L.m−2h−1), salt rejection (from 40 to 98%) and fouling resistance (33 to 88%). Optimum ZIF-8 to GO ratio was established as indicated in observed pure water flux, salt rejection and BSA fouling resistance. Therefore, a balance in hydrophilic and porous effect of the filler was observed to lead to this observed membrane behaviour suggesting that careful filler design can result in performance gain for thin film composite (TFC) membranes for water treatment application.

1 September 2020 in Chemical Engineering Journal Advances
Verified
Journal Article
Open access
TMThollwana Makhetha
Thollwana Makhetha
RMRichard Motlhaletsi Moutloali
Richard Motlhaletsi Moutloali

25 July 2015 in Polymer Composites
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Journal Article
Closed access
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TMTshwafo Motaung
Tshwafo Motaung
MMMokgaotsa Mochane
Mokgaotsa Mochane
TMThollwana Makhetha
Thollwana Makhetha
SMSetumo Motloung
Setumo Motloung
Thabang Hendrica MokhothuThabang Hendrica Mokhothu
Thabang Hendrica Mokhothu
RMRantooa Moji
Rantooa Moji

26 July 2025 in Chemical Engineering Journal Advances
Verified
Journal Article
Open access
CHChloe G Hahn
Chloe G Hahn
SMSoraya P Malinga
Soraya P Malinga
TMThollwana Makhetha
Thollwana Makhetha