To realize the effective profile control of a heavy oil reservoir, hydrolyzed polyacrylamide (HPAM) and water-soluble phenol-formaldehyde resin (PR) were chosen to prepare the profile control system, which gelled at medium or low temperatures and existed stably at high temperatures in the meantime. The effects of phenolic ratios, PR concentration, and HPAM concentration on the formation and strength of the gels were systematically studied by the gel-strength code method and rheological measurements. And the microstructure of the gels was investigated by scanning electron microscope measurements. The results showed that the gelling time of the HPAM-PR system was 13 h at 70 °C. The formed gel could stay stable for 90 days at 140 °C. In addition, the gels showed viscoelastic properties, and the viscosity reached 18,000 mPa·s under a 1.5 s−1 shearing rate due to their three-dimensional cellular network structure. The formation of the gels was attributable to the hydroxyl groups of the PR crosslinking agent, which could undergo the dehydration condensation reaction with amide groups under non-acidic conditions and form intermolecular crosslinking with HPAM molecules. And the organic crosslinker gel system could maintain stability at higher temperatures because covalent bonds formed between molecules.
Under the background that the in-depth profile control technology is gradually applied in low-permeability fractured reservoirs, this paper regards block H of Changqing Oilfield as the research object, referring to the range of its physical parameters and field application data. Three common in-depth profile control agents (PCAs), nanosphere suspension, poly(ethylene glycol) single-phase gel particle (PEG) and cross-linked bulk gel and swelling particle (CBG-SP), are selected to investigate the compatibility between the fractured channels and the PCAs through a series of experiments. The experimental results show that the nanospheres with particle sizes of 100 nm and 300 nm have good injectivity and deep migration ability, which remains the overall core plugging rate at a high level. The residual resistance coefficient of 800 nm nanospheres decreases in a “cliff” manner along the injection direction due to the formation of blockage in the front section, resulting in a very low plugging rate in the rear section. The injection rate is an important parameter that affects the effect of PEG in the fractured channels. When the injection rate is lower than 0.1 mL/min, the plugging ability will be weakened, and if the injection rate is higher than 0.2 mL/min, the core plugging will occur. The appropriate injection rate will promote the better effect of PEG with the plugging rate > 90%. The average plugging rate of CBG-SP in fractured rock core is about 80%, and the overall control and displacement effect is good. Based on the experimental data of PCAs, the optimization criteria of slug configuration and pro-duction parameters are proposed. According to the principle “blocking, controlling and displacing”, references are provided for PCAs screening and parameters selection of field implementation.
Three-dimensional (3D) seismic data and well log data were used to investigate the sandstone architecture of the Middle Jurassic deltaic reservoirs of the Zhetybay Oilfield, Mangeshrak Basin, Kazakhstan. The base-level cycles of different scales were identified and divided using well log and 3D seismic data. Five types of sedimentary boundaries were identified in the mouth bar sandstones. The boundaries divide single mouth bars. Vertically, the spatial distribution of sand bodies can be divided into superposed, spliced, and isolation modes. Laterally, contact modes can be divided into superposition, lateral, and isolation modes. We found that the base-level cycle controls the evolution of the delta front sand body architecture. In the early decline or late rise of the base-level cycle, the superimposed or spliced modes dominate the sand body. By contrast, the lateral or isolation modes dominate the sand body in the late decline or early rise of the base-level cycle. This paper proposes an architecture model of the delta front sand bodies controlled by the base-level cycle. The spatial distribution and morphological variation of deltaic sand bodies could be linked to the base-level cycles.
The water-flooded zone in a sandstone reservoir with a complex porosity–permeability relationship is difficult to interpret quantitatively. Taking the P Formation of Kalamkas Oilfield in Kazakhstan as an example, this paper proposed a reservoir classification method that introduces the J-function into the crossplot of resistivity and oil column height to realize the classification of sandstone reservoirs with a complex porosity–permeability relationship. Based on the classification results, the initial resistivity calculation models of classified reservoirs were established. The oil–water seepage experiment was performed for classified reservoirs to measure the lithoelectric parameters and establish the relationship between water production rate and resistivity for these reservoirs, and then water production was quantitatively calculated according to the difference between the inverted initial resistivity and the measured resistivity. The results show that the reservoirs with an unclear porosity–permeability relationship can be classified by applying the J-function corresponding to grouped capillary pressure curves to the crossplot of oil column height and resistivity, according to the group average principle of capillary pressure curves. This method can solve the problem that difficult reservoir classification caused by a weak porosity–permeability correlation. Moreover, based on the results of reservoir classification, the water production rate and resistivity model of classified reservoirs is established. In this way, the accuracy of quantitative interpretation of the water-flooded zone in the reservoir can be greatly improved.
The well productivity of high-waxy reservoirs is highly influenced by temperature changes. A decrease in temperature can cause the precipitation of wax from the crude oil, leading to a decrease in the formation’s drainage capacity and a drop in oil production. In this study, the wax precipitation of crude oil is characterized by rheological properties tests and differential scanning calorimetry (DSC) thermal analysis. The wax damage characteristics of cores and the relative permeability curves at different temperatures were investigated through coreflood experiments. Furthermore, nanoemulsion is selected as a chemical agent for injection fluid. The nuclear magnetic resonance (NMR) scanning technique is used to investigate the effects of oil recovery enhancement at different pores by increasing temperature and adding nanoemulsion. By comparing the changes in T2 spectra and the distribution pattern of residual oil before and after liquid injection, the results have shown that both increasing temperature and adding nanoemulsion have a significant effect on oil recovery. The improvement of micropores is less pronounced compared to macropores. The produced oil mainly comes from the large pores. When the temperature is lower than the crude oil dewaxing point temperature, there is a serious dewaxing plugging phenomenon in the pores. Additionally, by observing the pattern of residual oil distribution at the end of the NMR online drive, it is hereby classified into wax deposition retention type, weak water washing retention type, and immobilized type, each with its own distinct characteristics. Wettability alteration and interfacial tension reduction can help to improve the drainage capacity of high-wax oil reservoirs, which is the main mechanism of nanoemulsion for enhanced oil recovery. These findings are highly valuable for enhancing the comprehension of the impact of highly waxed crude oils on drainage capacity and the ultimate oil recovery rate, particularly in relation to wax precipitation deposition.
In the present study, we used Kalamkas, which is a typical Kazakhstani oilfield, which produces wastewater with high Ca2+/Mg2+ and Fe2+ concentrations, as a case study. We investigated a method for preparing Fe2+ polymer solutions without oxygen isolation under the conditions of salinity >110 × 103 mg/L, Ca2+/Mg2+ concentration >7000 mg/L, and Fe2+ concentration >30 mg/L. Fe2+-resistant groups were grafted onto the molecular chains of a hydrophobically associating polymer prepared using existing synthesis technology to overcome the decrease in apparent viscosity of the polymer solution due to the oxidation of Fe2+ during solution preparation. The experiments showed that PAM-IR with iron-resistant groups can be completely dissolved in the wastewater within 180 min, and can tolerate an NaCl concentration of up to 0.23 × 106 mg/L, a Ca2+ concentration of up to 10 × 103 mg/L, an Mg2+ concentration of up to 9 × 103 mg/L, and a Fe2+ concentration of up to 90 mg/L, with favorable thickening performance and resistances to NaCl, Ca2+, Mg2+, and Fe2+. PAM-IR has good injection performance and can establish a high resistance factor (FR) and residual resistance factor (FRR) to increase the sweep efficiency. Therefore, it is potentially useful for enhancing oil recovery.