Green methanol could play a major role in decarbonising both the chemical and energy sectors. While techno-economic and environmental studies on green methanol following a life-cycle perspective are available, its social implications from a supply-chain standpoint remain largely unexplored. In order to fill this gap, this work presents the first social life cycle assessment of green methanol produced with CO₂ directly captured from the air and hydrogen from wind power electrolysis. When compared to conventional methanol from natural gas, the results suggest an unfavourable performance of green methanol under negative social indicators (forced labour, women in the sectoral labour force, health expenditure, social responsibility promotion, and fair salary) due to the increased supply-chain complexity of the green system. In contrast, green methanol would outperform its conventional counterpart in terms of sectoral contribution to economic development, a positive social indicator which would benefit from the increase in working hours. Besides future consideration of a higher number of positive indicators and potential improvements in country- and sector-specific risk levels towards high-quality social and working conditions, an enhanced social life-cycle performance of green methanol requires technical improvements to reduce the high demand for energy inputs and equipment across its supply chain. Acknowledging decarbonisation as the actual driver of green methanol deployment, future social studies are suggested to focus on the comparison of renewable alternatives for its production and the effect of social regulations.