The conducted research aimed to evaluate the influence of admixtures of various modified starches on the rheological properties of cement composites and their influence on the compressive strength of hardened cement mortars. The study involved 17 different modified starch admixtures. Using a rheometer, the values of viscosity and tangential stresses were determined depending on the shear rate, and were subsequently used to determine the yield point and plastic viscosity of cement slurries. The next parameters tested were the flow of fresh cement slurry and the compressive strength of hardened cement composite. The highest fluidisation was recorded for retentate LU-1420-0.5%Ac-R, an increase of 82%. The conducted tests led to the conclusion that admixing cement composites with modified starches changes the rheological parameters and the compressive strength of cement composites. The highest strength gains occurred for the admixtures of retentate LU-1412-R (increase of 25%). Declines in compressive strength were noticed in the retentate LU-1422-R (decrease by 13%) and the retentate OSA-2.5%-R (decrease of 17%). The admixture of starch hydrolysate significantly decreases the yield point of slurries, which in turn may contribute to the fluidisation of concrete mixes and the reduction of mixing water. The lowest values were obtained for retentates LU-1420-0.5%Ac-R (decrease of 94%), and LU-1412-R (decrease of 93%). It was found that the consistency and compressive strength of cement mortars are affected by both the type of modification and the length of the chemical chain of starch.
Growing interest in the use of natural organic compounds in the production of green concrete with the use of plasticizers has been particularly noticeable in the literature of recent decades. Starch is an attractive material due to its abundance, the low cost of sourcing it, and its biodegradability, biocompatibility, and susceptibility to modification. The objective of the study was to evaluate the effect of starch hydrolysate additives on the physicochemical properties of cement composites and concrete. Compressive strength tests and cement slurry rheology measurements were carried out for water–cement ratios from 0.40 to 0.50 and for amounts of added dextrin from 0.0 to 0.7% in relation to the cement weight. The dextrins used were characterized in terms of their viscosity, polymerisation degree, and surface activity in air/water systems. Conducted research indicates that even the minimum content of dextrin increases the fluidization of cement mixes (the flow diameter increased by 67.5% compared with the mixture without the admixture), enables the reduction of mixing water, and contributes to the compressive strength of cement mortars. A further decrease in the w/c ratio to the value of 0.40 resulted in an increase in the strength value of up to 67.9 MPa, which provided a 40% increase in strength. The degree of the polymerisation of added dextrin is seen as having an effect on the physical parameters of the cement mortar; the shorter the polymer chain of the studied dextrin, the more packed the adsorbent layer, and the greater the flow diameter of the cement mortar.
18 January 2022 in Polish Journal of Environmental Studies
The leading theme of the paper was to study, how the use of lightweight concrete based on waste aggregates, characterized by significant mechanical strength and increased thermal insulation, affects the properties of building partitions and contributes to possible economic savings, so as to properly design and select materials required for the construction process. The work presents the composition of lightweight concrete samples made of waste lightweight aggregates as well as their physical and mechanical properties. It includes calculations concerning floor loading and heat transfer coefficient of building partitions made of the presented lightweight concretes. Calculations provided the basis for assessing the impact of particular parameters on compressive strength and thermal insulation of walls and floors. The paper additionally describes concretes made of waste aggregates in the form of lytag (Pollytag) and slag. Based on the research, it was found that concrete containing Pollytag had the lowest density value and thermal conductivity coefficient. These parameters translated into reduction in the weight of the slab in question by more than 40% and allowed to save 25% of steel compared to an analogous plain concrete slab. The decrease in heat conductivity coefficient did not result in a significant increase in thermal insulation of building partitions.
Sulfate corrosion is a significant durability issue for concrete used in sewage and hydraulic infrastructure. In sulfate-rich environments, the formation of expansive products (e.g., ettringite and thaumasite) leads to a progressive loss of performance. Unlike conventional protection methods, which rely on surface-applied coatings or impregnation, this study examines the use of water-dilutable epoxy resins as an internal, volume-wide admixture dispersed throughout the concrete matrix to provide whole-body protection. The experimental program evaluated the mechanical performance, microstructure, and sulfate ion ingress/penetration dynamics of resin-modified concretes. The results suggest that using the appropriate amount of resin can limit the penetration of aggressive ions and slow the harmful changes associated with sulfate attack while maintaining the material’s overall performance. Overall, these findings suggest that water-based epoxy admixtures are a promising strategy for improving the durability of concrete in sulfate-exposed environments. They also provide guidance for designing more resistant cementitious materials for modern infrastructure applications.
The manuscript presents research focusing on the adsorption and emulsion properties of starch hydrolysates modified through acetylation, oxidation, and cross-linking. The techniques used in this study included measurements of equilibrium surface tension (du Noüy ring) dynamic surface tension (drop shape analysis), and the preparation and evaluation of emulsion stability (TURBISCAN). The surface activity of the acetylated starch hydrolysates is affected by the degree of acetylation. The acetylated starch 0.02Ac-H exhibited higher surface activity than the more highly substituted derivative 0.1Ac-H. Furthermore, it was shown that the surface activity of the components increased as the acetylated oxidized starch underwent hydrolysis. The fractions collected after 180 min using a membrane with a low separation capability (8 kDa) revealed the highest capacity for reducing surface tension. In binary systems consisting of starch derivatives and surfactants, synergistic effects in reducing surface tension were particularly noticeable in systems containing ionic surfactants. The addition of a cationic surfactant to the modified starch hydrolysate solution (1:6 mol/mol) resulted in a significantly more efficient saturation of the air/water interface. This study demonstrated that emulsions stabilized with modified starch hydrolysates remained stable over time, even when these hydrolysates constituted up to 60% of the emulsifier mixture.