Two-dimensional (2D) ZnO nanowalls were prepared on a glass substrate by a low-temperature thermal evaporation method, in which the fabrication process did not use a metal catalyst or the pre-deposition of a ZnO seed layer on the substrate. The nanowalls were characterized for their surface morphology, and the structural and optical properties were investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and photoluminescence (PL). The fabricated ZnO nanowalls have many advantages, such as low growth temperature and good crystal quality, while being fast, low cost, and easy to fabricate. Methane sensor measurements of the ZnO nanowalls show a high sensitivity to methane gas, and rapid response and recovery times. These unique characteristics are attributed to the high surface-to-volume ratio of the ZnO nanowalls. Thus, the ZnO nanowall methane sensor is a potential gas sensor candidate owing to its good performance.
1 January 2022 in Journal of the Mechanical Behavior of Biomedical Materials
Palladium-coated copper wire with a flash-gold layer (PCA) is an oxidation-resistant fine wire that simultaneously has the properties of palladium-coated copper wire (PCC) and gold-coated copper wire. This research used an extreme sulfidation test to compare corrosion resistance between the PCC and PCA wires. In addition to closely examining the morphology of the wires, the internal matrix after the sulfidation test is also discussed. In doing so, the PCA wire was bonded onto the aluminum pads and the sulfidation test was conducted. Then, we observed its morphology and elemental distribution and found that the flash-gold layer of the PCA wire effectively enhanced resistance to sulfidation corrosion. Because the copper ball had an alloying effect on the ball bonding, it produced different shapes of sulfide after the sulfidation test. The degree of corrosion on the wedge bond was different because of the presence or absence of the coated layer. In contrast, the flash-gold layer of the PCA wire enhanced the bonding force and retained low resistance characteristics after the sulfidation test.
Sn-xZn (x = 9, 25, and 50 wt%) alloy solders are applied in photovoltaic (PV) ribbon and connected with silicon solar cells. The interfacial microstructures, series resistance, and bonding strength of Sn-xZn PV modules are investigated. Cu 5 Zn 8 and AgZn 3 intermetallic compounds (IMCs) were found at the interfaces. The Zn content in the solder dominates the growth behavior of IMCs at the interface. The thickness of the Cu 5 Zn 8 and AgZn 3 IMC layer increased with increasing Zn content in the solder, and thus, the series resistance of the PV module also increased. The growth of IMCs can enhance the interfacial adhesion strength, but excess Zn overconsumes the Ag electrode, reducing the bond strength of the PV module. Applying low-Zn-content Sn- xZn solder to PV ribbon avoids overconsumption of the Ag layer and, thus, decreases the series resistance and internal stress.
This study applied plasma transferred arc (PTA) welding to fabricate hard cladding layers by using nickel-based superalloy (NCR7) and niobium carbide (NbC) powders as filler material. The resultant composite claddings were coated onto ductile iron and then analyzed to understand the effect of different quantities of NbC on the solidification structures of the cladding layers and on the characteristics of the interface between the cladding layers and the ductile iron. Cutting tests were also conducted to assess the morphology and mechanism of flank wear on PTA NbC/NCR7 composite cladding tools. The results revealed that the cladding specimens’ microstructures comprised a mixture of dendrites and interdendritic eutectics along with a considerable quantity of carbides (MC, M7C3, and M23C6) scattered within the γ-Ni matrix. Incorporating considerable NbC carbide enhanced the claddings’ surface hardness, but it had a limited effect on improving the flank wear on the turning tools. The flank wear on the composite cladding tools intensified as the NbC content was increased. The wear behavior, defined by brittle fractures and stripped NbC particles, led to a decline in turning tool performance. Accordingly, the Ni-based alloy composite cladding with larger NbC particles appears more suitable for sliding or erosion applications under normal stress conditions.
1 October 2014 in Nanoscience and Nanotechnology Letters