The present study aims at investigating the effect of process parameters on environmental sustainability of 3D printing of short fiber-reinforced polymer composites. A preliminary study allowed defining the printing parameters, in terms of printing speed, extrusion temperature and layer thickness, which guarantee low energy consumption. Then, the environmental behavior of two 3D printable composite materials, glass fiber-reinforced (GlassPA) and carbon fiber-reinforced (CarbonPA) polyamide, was investigated using the Life Cycle Assessment methodology, to provide a comprehensive overview of the considered materials and to support the sustainable development of industrial additive manufacturing processes. The functional unit was chosen taking into account the mechanical properties of the two short fiber-reinforced composites. To this purpose, tensile and flexural tests were performed on specimens produced by Fused Filament Fabrication process to evaluate the mechanical properties of printed materials. Scanning electron microscopy was used to observe the different filament morphology affecting the materials performances. Experimental tests showed that CarbonPA exhibits mechanical performances higher than those of GlassPA. Due to the weight reduction that can be accomplished by means of carbon fibers, CarbonPA results the most environmentally friendly alternative in tensile loads applications. On the contrary, for flexural loads applications, GlassPA exhibits lower environmental footprint.

The present paper aims at studying the effect of geometric parameters and moisture content on the mechanical performances of 3D-printed isogrid structures in short carbon fiber-reinforced polyamide (namely Carbon PA). Four different geometric isogrid configurations were manufactured, both in the undried and dried condition. The dried isogrid structures were obtained by removing the moisture from the samples through a heating at 120 °C for 4 h. To measure the quantity of removed moisture, samples were weighted before and after the drying process. Tensile tests on standard specimens and buckling tests on isogrid panels were performed. Undried samples were tested immediately after 3D printing. It was observed that the dried samples are characterized by both Young modulus and ultimate tensile strength values higher than those provided by the undried samples. Similar results were obtained by the compression tests since, for a given geometric isogrid configuration, an increase in the maximum load of the dried structure was detected as compared to the undried one. Such discrepancy tends to increase as the structure with the lowest thickness value investigated is considered. Finally, scanning electron microscopy was carried out in order to analyze the fractured samples and to obtain high magnification three-dimensional topography of fractured surfaces after testing.

Robotic Automated Fiber Placement (R-AFP) technology was developed to manufacture composite laminates by placing carbon fiber thermoset towpregs, obtained by impregnating 12 K high-strength grade carbon fibers in an epoxy resin system. In order to avoid placement induced defects, a thermographic scanning technique was implemented for on-line quality monitoring of the R-AFP process. The thermal analysis proved to be an effective and quick approach for the real-time detection of deposition defects generated during. The R-AFP process was performed by applying a constant pressure through the compaction roller; different pressure values were investigated. The effect of the resin weight fraction and compaction pressure on the mechanical properties applied by the deposition head during R-AFP of cross-ply laminates was studied. The reduction of the tensile strength and the increase of the elastic modulus with decreasing pressure of the compaction roller was observed. Furthermore, the values of ultimate tensile strength and elastic modulus decrease as the resin content increases. Finally, the three-dimensional topography of surface fracture of tensile samples was investigated by means of the optical and scanning electron microscopy.

A widespread problem of manufacturing processes is represented by the occurrence of tool wear that can lead to both poor surface finish and poor mechanical properties in the workpiece. This issue affects also additive manufacturing technologies such as the material extrusion technique. In this process, the wear mechanisms of the extrusion nozzle can be severe, in particular when materials with a high abrasive capacity, such as carbon fiber-reinforced polymers, are 3D printed. Despite the significance of this problem, scientific literature lacks systematic evaluations of nozzle wear and its correlation with parts mechanical properties. In this framework, the present paper aims at investigating the effect of the nozzle wear evolution on the mechanical properties of additively manufactured parts in short carbon fiber-reinforced polyamide. To this purpose, 3D printing processes were performed. The time dependence of the nozzle wear was analyzed by interrupting the additive manufacturing process at fixed time intervals. To analyze the effect of nozzle wear on the mechanical performances of printed parts, tensile specimens were 3D printed and tested at room temperature. A reduction in mechanical performances of the printed samples and a worsening in the surface quality were observed with increasing the nozzle wear. Optical microscopy investigation and X-ray computed tomography were used to monitor the external and internal nozzle wear evolution. The surface roughness measurements were performed to evaluate the surface quality of the 3D printed parts. Furthermore, the scanning electron microscopy was used to observe the three-dimensional topography of the longitudinal sections of filament in Carbon PA, at different printing time values, and fractured surfaces of tensile samples. This study can help to better understand nozzle wear and to predict tool service life for industrial applications. In addition, it can prompt future studies focused on the reduction of tool wear.

Additive manufacturing is a promising and emerging technology that can transform the global manufacturing and logistics by cutting costs and times of production. Localized corrosion resistance properties of 0°, 45°, and 90° build-up orientations of 17-4 PH as-sintered samples, manufactured by means of Bound Metal Deposition (BMD), have been investigated by electrochemical and morphological investigations. The cyclic potentiodynamic polarization curves and the open circuit potential monitoring, together with potential drop analysis, revealed that the BMD localized corrosion resistance properties were lowered if compared to a wrought 17-4 PH: a characteristic anodic behavior and many drops in potential were recorded for BMD, whilst the wrought specimens presented a typical passive behavior with pitting corrosion. Morphological investigations by scanning electron microscopy and energy-dispersive X-ray analysis revealed the presence of porosities and defects, especially for the 90° build-up orientation, and inclusions of SiO₂. The 45° build-up orientation showed the best corrosion resistance properties among all the BMD specimens, even though defects and porosities were observed, suggesting that their morphology and geometry influenced the overall corrosion behavior.