Basalt fiber (BF) has a high mechanical strength, excellent temperature resistance, good chemical stability, low energy consumption, and an environmentally friendly production process. In addition, BF-reinforced polymers (BFRPs) have good corrosion resistance and designability; thus, they meet the application requirements of electrical equipment, such as new conductors, insulating pull rods, and composite cross-arms. However, there are still a series of technical issues in the mass production of BF, and the stability of the products needs to be further improved. Therefore, the research on the production, modification, and application of BF is necessary. This paper discusses the chemical composition and production technology of BF, describes the morphology and properties of BF, summarizes the interface problems and modification methods of composites, and finally, introduces the application prospects of BF in the field of electrical materials, which is expected to provide a reference for the application and promotion of BFRP in the future.

Basalt fibre composite materials have shown good application prospects in electrical equipment, but their reliability can be affected by damp‐heat ageing. In this work, the interface, mechanical, and electrical properties of basalt fibre composites treated with three coupling agents via damp‐heat ageing were compared. Molecular simulations were conducted to reveal the damp‐heat ageing mechanism of the composites. The results show that γ ‐aminopropyl triethoxy silane (KH‐550) and γ ‐glycidoxy propyl trimethoxy silane (KH‐560) perform better as coupling agents as they form bonds with the matrix resin, compared with γ ‐methacryloxy propyl trimethoxy silane (KH‐570). After the damp‐heat ageing treatment, the hydrolysis of the defects of the amino groups in the interface of the KH‐550‐treated sample can weaken its mechanical properties and insulation properties greatly. The interface layer of the KH‐560‐treated sample is mostly composed of carbon–oxygen single bonds and methylene groups with its interface structure more stable, which endows the sample with better stability of its mechanical and insulating properties. Therefore, KH‐560 is a more suitable coupling agent for processing basalt fibres to be used in electrical equipment.

In order to promote the application of composite insulators in coastal areas with high temperature, high humidity and high salt, it is of great importance to develop matrix resin with salt corrosion resistance for composite core rods. In this study, bisphenol A epoxy resin was modified by blending with alicyclic epoxy resin (2021P). Three different proportions of 2021P/DGEBA blend resins (0% 2021P/DGEBA, 10% 2021P/DGEBA and 20% 2021P/DGEBA) were prepared, and the high salt medium corrosion test was carried out. The physicochemical (FTIR, DMA, TGA) and electrical properties (dielectric loss, leakage current and breakdown field strength) of the blend resin before and after aging were tested and analyzed, and the optimal blend proportion was determined. The results showed that after salt aging, the Tg of 0% 2021P/DGEBA decreased to 122.99 °C, while the Tg of 10% 2021P/DGEBA reached 134.89 °C; The leakage current of 0% 2021P/DGEBA increased to 48.994 μA, while that of 10% 2021P/DGEBA only increased to 44.549 μA; The breakdown field strength of 0% 2021P/DGEBA dropped to 40.36 kv/mm, while that of 10% 2021P/DGEBA only dropped to 43.63 kv/mm. The introduction of 2021P enhanced the salt corrosion resistance of the blend resin, which could hinder the penetration, diffusion and erosion of external media (such as Na⁺, Cl⁻, H₂O, etc.) to the matrix resin. The comprehensive properties of 10% 2021P/DGEBA blend system reached the best, which was better than other blending resins, showing great application potential.

With the application of the composite cross-arm in power systems, comprehensive anti-aging performance is a key factor to determine whether it can operate safely. In order to study the influence of the operating environment on the external insulation characteristics of composite cross-arms of distribution networks, various aging conditions such as voltage, rain, temperature, humidity, salt fog and ultraviolet light were simulated in a climate chamber based on the real operation conditions of the 10-kV composite cross-arm. A multi-factor aging test of composite cross-arms with two kinds of cross-section shapes (T-shaped and square) was carried out for 5000 h. The change trends of leakage current and flashover voltage of the composite cross-arms before and after aging were analyzed. Finally, the aging mechanism of the silicone rubber sheaths was analyzed to further explain the reasons for the change of external insulation performance of composite cross-arms. The results show that the leakage current rising rate of T-shaped and square composite cross-arms after aging increases significantly, and the minimum flashover voltage decreases to 58.3 kV and 49.502 kV, respectively. The results of FTIR, SEM and hydrophobic angle tests show that, after aging, the performance of the silicone rubber outer sheath material decreases in varying degrees. In general, UV aging has the greatest influence on the external insulation characteristics of composite cross arms. Generally speaking, after 5000 h of multi factor aging, although the external insulation characteristics of the 10-kV composite cross-arm decreases to a certain extent, there is still enough margin to meet the normal operation.