Inkjet printing of high-viscosity (up to 105 mPa·s) nanosilver inks is an interesting emerging technology to achieve the 3D fully printed fabrication of electronic products. The highly viscous force of the ink makes it impossible to achieve droplet ejection with the traditional piezoelectric-driven drop-on-demand inkjet method. In this study, a pneumatic needle jetting valve is adopted to provide sufficient driving force. A large number of high-viscosity inkjet printing tests are carried out, and the jetting behavior is recorded with a high-speed camera. Different jetting states are determined according to the recorded images, and the causes of their formation are revealed. Additionally, the effects of the operating pressure, preload angle, and fluid pressure on jetting states are elucidated. Furthermore, the jetting phase diagram is obtained with the characterization of the Reynolds number and the printable region is clarified. This provides a better understanding of high-viscosity inkjet printing and will promote the application of high-viscosity inkjet printing in 3D fully printed electronic products.
The powder bed selective laser process (sintering/melting) has revolutionised many industries, including aerospace and biomedicine. However, PBSLP of ceramic remains a formidable challenge. Here, we present a unique slurry-based approach for fabricating high-strength ceramic components instead of traditional PBSLP. A special PBSLP platform capable of 1000 °C pre-heating was designed for this purpose. In this paper, PBSLP of Al2O3 was accomplished at different SiC loads up to 20 wt%. Several specimens on different laser powers (120 W to 225 W) were printed. When the SiC content was 10 wt% or more, the chemical interaction made it difficult to process. Severe melt pool disturbances led to poor sintering and melting. The structural analysis revealed that the micro-structure was significantly affected by the weight fraction of SiC. Interestingly, when the content was less than 2 wt%, it showed significant improvement in the microstructure during PBSLP and no effects of LPS or chemical interaction. Particularly, a crack pinning effect could be clearly seen at 0.5 wt%.
Laser powder bed fusion is a laser-based additive manufacturing technique that uses a high-energy laser beam to interact directly with powder feedstock. LPBF of oxide ceramics is highly desirable for aerospace, biomedical and high-tech industries. However, the LPBF of ceramics remains a challenging area to address. In this work, a new slurry-based approach for LPBF of ceramic was studied, which has some significant advantages compared to indirect selective laser sintering of ceramic powders. LPBF of Al2O3 was fabricated at different MgO loads up to 80 wt%. Several specimens on different laser powers (70 W–120 W) were printed. The addition of magnesia influenced the microstructure of the alumina ceramic significantly. The findings show that when the laser power is high and the magnesia load is low, the surface quality of the printing parts improves. It is feasible to produce slurry ceramic parts without binders through LPBF. Furthermore, the effects of SiC and MgO loads on the microstructure and surface morphology of alumina are compared and analysed.
In the present work, a novel Ti-Al-C-Nb composite was prepared using in situ selective laser forming (ISLF). The formation mechanism of the Ti-Al-C-Nb bulks, which were synthesized using elemental titanium, aluminum, and carbon (graphite) powders via ISLF techniques, was investigated. The results showed that the Ti3Al and TiC phases were the dominant synthesis products during the chemical reactions, and these occurred during the ISLF process. The size of the fine nanoscale crystal TiC grains could reach 157 nm at an energy level of 60 J/mm3. The porous structure of the ISLF specimens was disclosed, and an open porosity of 20–44% was determined via the scanning speed and the laser power. Both the high dynamic viscosity and the reactions of the raw powders led to the generation of a considerable number of pores, whereas the specimen processed using 45 W and 100 mm/s possessed the lowest degree of open porosity.
13 February 2023 in Journal of the American Ceramic Society