Non-equilibrium conditions in plasma are often achieved by pulsed power delivery, where the pulse shape and repetition rate determine the properties of the plasma constituents and thus its chemical reactivity. The evaluation of the latter is becoming increasingly important to understand the observed effects, especially when new application fields are targeted. The composition of the plasma and the occurring chemical reactions can be calculated using various models. Thereby, the temperature of the electrons, the electron number density, as well as the heavy particle temperature are usually required as the basis of such calculations. In this work, the influence of pulse amplitude and repetition rate on these plasma parameters is determined by laser scattering for a low-current, high-voltage discharge operated with nitrogen at atmospheric pressure. In particular, the characteristic parameters regarding the plasma free electrons in such discharges have not yet been experimentally determined to this extent. The results are validated by spectroscopic measurements, i.e., the electron density is estimated from the Stark broadening of the hydrogen beta line and the heavy particle temperature is estimated by fitting the spectrum of nitrogen molecular transitions. Depending on the operating frequency, a pure nitrogen discharge with an input power of about 650 W displays an electron density between $1.7\times {10}^{21}{\mathrm{m}}^{-3}$ and $2.0\times {10}^{21}{\mathrm{m}}^{-3}$ with electron temperatures in the range of 40,000 K and heavy particle temperatures of about 6000 K in the core of the discharge channel. Furthermore, a relatively slow electron recombination rate in the range of 20 µs is observed.

The advantages of pulsed low-current high-voltage discharges operated at atmospheric pressure and the ease with which such discharges can be implemented industrially contributed to their popularity. However, the high reactivity of a pulsed plasma implies that thorough diagnostics are needed to fully understand the interactions inside these plasmas. Some of the key parameters determining plasma properties of low-current discharges are the electron number density and the temperature of heavy particles. Both parameters can be determined experimentally with spectroscopic techniques, for example by investigating the broadening of spectral lines due to the Stark effect and by fitting synthetic spectra to molecular transitions. To the authors’ knowledge, experimentally determined electron densities for pulsed low-current discharges operated in a power range between 300 W and 1000 W have not been performed in previous works. Thus, in this work, the electron number density and temperature of heavy particles of one of several commercially available plasma systems are determined by means of emission spectroscopy.

Recent research trends show an increasing interest in non-equilibrium plasmas operated at atmospheric pressure, which are often used to tackle several environmental and health issues. Nevertheless, due to the complexity of the applications, these trends also show the need for a comprehensive characterization of such plasmas for a deeper understanding of the observed effects. One of the diagnostic methods for experimental determination of key parameters which affect the reactivity of a plasma, i.e., electron temperature, electron density and heavy particle temperature, is laser scattering. In this work, an approach based on a simple and compact laser scattering setup is proposed, which allows an estimation of the above parameters without any additional changes in the acquisition settings. Thus, the experimental effort and possible sources of error can be reduced. The proposed setup is tested experimentally with a commercially available pulsed plasma system, and the results are compared to available data. From this comparison, it is found that the plasma parameters estimated with the proposed scattering setup are plausible.

The topic of water reuse is becoming increasingly important. It might be possible to use the well-known antibacterial effect of atmospheric pressure plasma due to its special mixture of reactive species, UV, and electromagnetic fields in a scaled-up, industrially interesting area to remove bacteria from wastewater, and thus, make it usable again. To review this question, water volumes of $5\mathrm{L}$ and of different qualities (turbidity and different degrees of hardness) were treated with a commercially available plasma system. The change in water-specific values such as pH, EC, ORP, nitrate, and nitrite content was determined. To test the antibacterial effect, both direct and indirect treatment of the test germ Pseudomonas aeruginosa was conducted. In the first case, the inoculated water samples were plasma-treated, while in the second case, the water samples were treated before inoculation with the germ. The viable bacteria were counted via the spread plate method. The best reduction rate of at least 6 log levels was achieved when inoculated deionized water samples were treated directly with plasma. A significant reduction in viability was also observed in directly treated clear tap water samples, whereby the different degrees of hardness did not influence the effectiveness of the plasma. The bacterial load remained almost unchanged when reused water samples from a car wash were treated. Based on the results, a possible application in a car wash was discussed including a cost estimation and possible limitations.

The plasma bulk velocity is one of the key parameters describing the behavior of a plasma jet and is relevant for applications such as plasma spraying or electric propulsion. Therefore, different measurement techniques to determine the velocity were developed in the past. This paper presents a novel, non-invasive method for spatially resolved velocity measurements. The method is based on tracking of characteristic features in tomographic reconstructions of the plasma plume. A high-speed image recording system combined with tomographic acquisition is therefore the backbone of this method. The proposed setup captures the object under study from six different directions at a frame rate up to one million frames per second, providing high spatial and temporal resolution. The tomographic reconstructions are then calculated using the ART algorithm to track features in the plasma fluctuations, from which the bulk velocity is determined. The setup was tested with a DC plasma torch operated at reduced pressures in the range of tens of millibars. For the analyzed parameters, the axial velocity reached a maximum of 1061 m/s at a distance of three centimeters from the plasma torch exit and decreased to 919 m/s further downstream at a distance of seven centimeters, which is in good accordance with previous work. Therefore, the proposed diagnostic method can serve as a non-invasive alternative to velocity measurements, providing additional information in the form of a 3D model of the plasma bulk.