The surface electron density significantly affects the photocatalytic efficiency, especially the photocatalytic CO₂ reduction reaction, which involves multi-electron participation in the conversion process. Herein, we propose a conceptually different mechanism for surface electron density modulation based on the model of Au anchored CdS. We firstly manipulate the direction of electron transfer by regulating the vacancy types of CdS. When electrons accumulate on vacancies instead of single Au atoms, the adsorption types of CO₂ change from physical adsorption to chemical adsorption. More importantly, the surface electron density is manipulated by controlling the size of Au nanostructures. When Au nanoclusters downsize to single Au atoms, the strong hybridization of Au 5d and S 2p orbits accelerates the photo-electrons transfer onto the surface, resulting in more electrons available for CO₂ reduction. As a result, the product generation rate of Au_SA/Cd_1−xS manifests a remarkable at least 113-fold enhancement compared with pristine Cd_1−xS.

Honeycomb-like g-C₃N₄ synthesized via thermal condensation of urea with the addition of water at low temperature, with ultralong carrier lifetime and outstanding photocatalytic activity for NOx removal.

A semimetal bismuth element exhibited admirable photocatalytic activity towards the removal of NO in air, and most strikingly, showed a catalytic “memory” capability, resulting from the surface plasmon resonance mediated direct photocatalysis.

Photocatalytic hydrogen evolution is a promising technique for the direct conversion of solar energy into chemical fuels. Colloidal quantum dots with tunable band gap and versatile surface properties remain among the most prominent targets in photocatalysis despite their frequent toxicity, which is detrimental for environmentally friendly technological implementations. In the present work, all-inorganic sulfide-capped InP and InP/ZnS quantum dots are introduced as competitive and far less toxic alternatives for photocatalytic hydrogen evolution in aqueous solution, reaching turnover numbers up to 128,000 based on quantum dots with a maximum internal quantum yield of 31%. In addition to the favorable band gap of InP quantum dots, in-depth studies show that the high efficiency also arises from successful ligand engineering with sulfide ions. Due to their small size and outstanding hole capture properties, sulfide ions effectively extract holes from quantum dots for exciton separation and decrease the physical and electrical barriers for charge transfer.