A new analytical method for defining the nonlinear bond stress–slip models of fiber reinforced plastics (FRP) sheet–concrete interfaces through pullout bond test is proposed. With this method, it is not necessary to attach many strain gauges on the FRP sheets for obtaining the strain distributions in FRP as well as the local bond stresses and slips. Instead, the local interfacial bond stress-slip models can be simply derived from the relationships between the pullout forces and loaded end slips. Based on a series of pullout tests, the bond stress–slip models of FRP sheet–concrete interfaces, in which different FRP stiffness, FRP materials (carbon FRP, aramid FRP, and glass FRP), and adhesives are used, have been derived. Only two parameters, the interfacial fracture energy and interfacial ductility index, which can take into account the effects of all interfacial components, are necessary in these models. Comparisons between analytical results and experimental ones show good accordance, indicating the rel...

Pore size distribution is an important factor that affects the moisture diffusion and permeability properties of cement-based materials. For cement paste, it is assumed that the mesopores (100 nm–0.01 mm) and macropores (0.01 mm–1 cm) can be neglected compared to the micropores ($<100\mathrm{nm}$ ). Based on the surface energy theory, moisture chemical potential of pore water is introduced to explain the liquid-gas equilibrium in pores with different radius. Using chemical potential as an intermedium, a quantitative relationship between micropore size distribution and water adsorption isotherms can be established. The micropore size distribution can be treated as an explanation of the moisture adsorption behavior, and by using adsorption isotherms, the micropore size distribution can be estimated conveniently. Mortar and concrete can be regarded as a combination of cement paste and aggregates; thus, besides the micropores, the mesopores and macropores are also taken into consideration. Finally, the general empirical estimation equations for pore-size distribution are developed for cement, mortar, and concrete, which can be used for refined modeling and simulating of durability-related issues, such as frost action, water permeability, and drying shrinkage.

Strengthening by fiber-reinforced polymers (FRPs) is one of the most common solutions to the ageing infrastructures. However, long-term durability of such systems under different environmental conditions needs to be understood properly before widely adopting these methods in the field. This paper presents research outcomes from an experimental program carried out to determine the influence of moisture on the durability of the bond between FRP and concrete along with its constituent materials. Performance was evaluated through single lap shear bond tests and various kinds of tests on the resin samples, including water absorption, mechanical characterization, and glass transition temperature ($T_g$ ) analysis. The specimens were exposed to continuous water immersion and wet-dry cycles for a maximum period of up to 24 and 18 months, respectively. The results show some deterioration on the material and the bond properties in both exposure conditions. The bond strength decreased up to 32 and 12% for high-strength and normal-strength concrete substrates, respectively, after continuous immersion, indicating the key role of the substrate in the durability of bonds. As a result of exposure, failure propagated towards the primer-concrete interface region. The failure mode changed from concrete cohesion to primer-concrete mixed failure for normal-strength concrete and from mixed failure to complete adhesion failure in case of high-strength concrete. These shifts in failure patterns are mainly due to destruction of the adhesion bond caused by water molecules at the interface. However, it is found that the loss of the adhesion bond is somehow compensated by the good mechanical interlocking obtained by proper surface roughness condition of the substrate. Finally, the effects of water were also investigated in interfacial bond stress-slip laws and fracture energies.