Precipitation is considered a key factor influencing the fluorescent dissolved organic matter (FDOM) of urban rivers. However, the multiple effects of precipitation on FDOM in urban rivers and the long-term impacts of precipitation on the spatial patterns of FDOM are seldom known. Spatiotemporal variations of FDOM at 36 sites from the urban rivers of Jinan City during dry and wet seasons were investigated in this study. Four components were identified using an excitation–emission matrix and parallel factor analysis. Overall, the total fluorescence intensities in dry and wet seasons ranged from 6.59 to 35.7 quinine sulfate units (QSU) and 3.42 to 69.3 QSU, respectively. Significant variations were found for different components that C2 and C3 declined but C4 increased in the wet season (p < 0.05). The temporal variations for different components could be explained by the different combined effects of precipitation dilution and flushing. Three different reference FDOM sources, including background water, spring water, and wastewater treatment plant (WWTP) outlets, were illustrated using principal coordinate analysis (PCoA). The places of FDOM in most sites were more closed to the PCoA location of WWTP outlets in the dry season while central shifted in the wet season. The changes of FDOM sources in the wet season could be explained by the mixed effect of precipitation. In conclusion, this study provided new insights into the multiple impacts of precipitation on FDOM in urban river systems, and also data support for precise pollution discharge and water resource management.

The spatial distribution of water storage capacity has always been the critical content of the study of saturation-excess runoff. Xin’anjiang model uses the water storage capacity curve (WSCC) to characterize the distribution of water storage capacity for runoff yield calculation. However, the mathematical and physical foundations of WSCC are unclear, which is impossible to simulate runoff generation with complex basins accurately. To fill this gap, we considered the dominant role of basin physical characteristics in water storage capacity and developed a new integrated approach to solve the spatial distribution of water storage capacity (L-WSCC) to account for the spatiotemporal dynamics of their impact on runoff generation. The main contribution of L-WSCC was to confer WSCC more physical meaning and the spatial distribution of water storage capacity was explicitly represented more accurately, so as to better express the runoff generation and provide a new approach for runoff yield calculation in non-data basin. L-WSCC was applied to Misai basin in China and promising results had been achieved, which verified the rationality of the method (the mean Nash–Sutcliffe efficiency (NSE):0.86 and 0.82 in daily and hourly scale, respectively). Compared with WSCC, the performance of L-WSCC was improved (mean NSE: 0.82 > 0.78, mean absolute value of flood peak error (PE): 12.74% < 21.66%). Moreover, the results of local sensitivity analyses demonstrated that land-use and land cover was the major driving factor of runoff yield (the change of mean absolute error (ΔMAE): 131.38%). This work was significant for understanding the mechanisms of runoff generation, which can be used for hydrological environmental management and land-use planning.