The PROSPECT model has been widely used to estimate leaf biochemical constituents, but retrieval of leaf mass per area (LMA) in fresh leaves has proved to be difficult due to the predominant water absorption in the infrared spectral region. At wavelengths where water absorption is low, both LMA absorption and light scattering are relatively high. Therefore, the uncertainty in scattering simulation at these wavelengths will lead to a relatively large error in LMA estimation. In this paper, we introduce a wavelength-independent factor to represent the first-order effect of anisotropic scattering in the elementary layer in the modified model PROSPECT-g, aiming at appropriately simulating leaf optical properties in spectral regions with high scattering and thus reducing the uncertainty in LMA estimation. In order to avoid introducing a new variable to be retrieved in model inversion, this factor is an intermediate variable derived from measured near infrared region spectral data and other existing model parameters. Results show that about 30%-40% of the tested samples are well simulated using PROSPECT-5, while for the rest of the samples simulation is greatly improved with PROSPECT-g. Leaf reflectance and transmittance reconstructions using PROSPECT-g are improved, especially at wavelengths with high scattering such as 750-1400 and 1500-1850 nm. LMA retrieval is significantly improved, with the average root-mean-square error decreasing from 38.7 (PROSPECT-5) to 16.6 g/m² (PROSPECT-g) for 628 leaves after considering anisotropic scattering in the elementary layer. Improvements are particularly noticeable for leaves with extremely high LMA contents.

Water turbidity is an important indicator of water quality, which regulates primary production by changing the light field in the water column. Thus, monitoring the spatial and temporal variations in water turbidity is environmentally and biologically important. In this study, nine commonly used spectral index algorithms were tuned using in situ data collected from two field surveys in the Pearl River Estuary of China, and the spectral ratios between the red and green bands (i.e., and ) were selected as the optimal indicator to estimate water turbidity in this region. A long‐term environmental data record of water turbidity was established for the Pearl River Estuary by applying the proposed algorithm to MODIS/Aqua data covering the estuary from 2003 to 2019. Water turbidity in the Pearl River Estuary has significantly decreased at a rate of 0.11 nephelometric turbidity units (NTU) per year (R² = 0.84, p < 0.01). The decline in water turbidity is linked with sea‐level rise in this area. Sea‐level rise may cause the longitudinal and lateral landward retreat of estuarine turbidity maxima (ETMs), directly contributing to the decline in water turbidity. Further, the sea‐level rise and the decline in water turbidity in the Pearl River Estuary are also two effects resulting from similar processes, such as urbanization. A high degree of correlation was observed between the water turbidity and salinity, which could facilitate promising monitoring of the increasingly severe saltwater intrusions in this region.

Light use efficiency (LUE) models are widely used to estimate gross primary productivity (GPP), a dominant component of the terrestrial carbon cycle. Their outputs are very sensitive to LUE. Proper determination of this parameter is a prerequisite for LUE models to simulate GPP at regional and global scales. This study was devoted to investigating the ability of the photochemical reflectance index (PRI) to track LUE variations for a sub-tropical planted coniferous forest in southern China using tower-based PRI and GPP measurements over the period from day 101 to 275 in 2013. Both half-hourly PRI and LUE exhibited detectable diurnal and seasonal variations, and decreased with increases of vapor pressure deficit (VPD), air temperature (Ta), and photosynthetically active radiation (PAR). Generally, PRI is able to capture diurnal and seasonal changes in LUE. However, correlations of PRI with LUE varied dramatically throughout the growing season. The correlation was the strongest (R2 = 0.6427, p < 0.001) in July and the poorest in May. Over the entire growing season, PRI relates better to LUE under clear or partially cloudy skies (clearness index, CI > 0.3) with moderate to high VPD (>20 hPa) and high temperatures (>31 C). Overall, we found that PRI is most sensitive to variations in LUE under stressed conditions, and the sensitivity decreases as the growing conditions become favorable when atmosphere water vapor, temperature and soil moisture are near the optimum conditions.

Nitrogen is an essential nutrient in many terrestrial ecosystems because it affects vegetation’s primary production. Due to the variety of nitrogen-containing substances and the differences in their composition across species, statistical approaches are now dominant in remote sensing retrieval of leaf nitrogen content. Many studies remove spectral regions characterized by strong water absorptions before retrieving nitrogen content, because water is believed to mask the absorption features of nitrogen. The objectives of this study are to discuss the necessity of this practice and to explore how water absorption affects leaf nitrogen estimation. Spectral measurements and chemical analyses for Maize, Sawtooth Oak, and Sweetgum leaves were carried out in 2014. The leaf optical properties model PROSPECT5 was used to eliminate the influences of water on the measured reflectance spectra. The inversion accuracy of PROPECT5 for chlorophyll, carotenoid, water, and dry matter of Maize was also discussed. Measured, simulated, and water-removed spectra were used to: (1) find the optimal nitrogen-related spectral index; and (2) regress with the area-based leaf nitrogen concentration (LNC) using the partial least square regression technique (PLSR). Two types of spectral indices were selected in this study: Normalized Difference Spectral Index (NDSI) and Ratio Spectral Index (RSI). Additionally, first-order derivative forms of measured, simulated, and water-removed spectra were devised to search for the optimal spectral indices. Finally, species-specific optimal indices and cross-species optimal indices, as well as their root mean square errors (RMSE) and coefficients of determination (R²), were obtained. The Ending Top Percentile (ETP), an indicator of the performance of cross-species optimal indices, was also calculated. PLSR was combined with leave-one-out cross validation (LOOCV) for each species. The predicted root mean square errors (RMSEP) and predicted R² were finally calculated. The results showed that chlorophyll, carotenoid, and water contents could be estimated with R² of 0.75, 0.59, and 0.69, respectively, which were acceptable for fresh leaves. The dry matter was retrieved with a relatively lower accuracy because of the fixed absorption coefficients adopted by PROSPECT5. The performances of species-specific optimal indices using water-free spectra were comparable to or worse than the corresponding indices derived with measured or simulated spectra. Compared with measured spectra, ETP did not change much after the effects of water were removed, and the R² between cross-species optimal spectral indices and area-based LNC for Sawtooth Oak and Sweetgum decreased while it remained almost the same for Maize, suggesting that the water-removed cross-species optimal indices were inferior to the corresponding optimal indices found without water removal. ETP was larger than 30% for all spectra, demonstrating the non-existence of common optimal NDSI or RSI for the three species. After water removal, the accuracy of PLSR for Sawtooth Oak and Sweetgum decreased and increased negligibly for Maize. The results suggest that water absorption has limited effects on reducing the accuracy of leaf nitrogen estimation. On the contrary, the accuracy may decrease due to the loss of spectral information caused by the removal of water-sensitive spectral regions.

Leaf Incorporating Biochemistry Exhibiting Reflectance and Transmittance Yields (LIBERTY) models the effects of leaf biochemical concentrations on reflectance spectra on the basis of Melamed theory, which has several limitations. These are: (1) the radiation components are not treated satisfactorily; (2) the directional changes of both particle and sublayer scattering ratios are not considered; and (3) the boundary constraint which makes needle leaves different from broadleaves is not included. Proofs of these limitations as well as theoretical improvements are given in this study. Global sensitivity analysis (SA) of three models: the original LIBERTY, our improved LIBERTY (LIBERTY_im) and The optical PROperties SPECTra model (PROSPECT) suggests that compared with LIBERTY, the global reflectance and transmittance of LIBERTY_im are more sensitive to diametrical absorbance $\alpha d$ —a parameter related to leaf biochemistry. Moreover, the global reflectance and transmittance of LIBERTY_im and PROSPECT had similar sensitivity patterns to the input variables, demonstrating indirectly the validity of our improvements over LIBERTY. However, neither LIBERTY nor LIBERTY_im considers boundary constraints, which limits their applications in modelling needle leaf optical properties. We introduced a particle string model, which might be used to simulate needle leaf optical properties in the future.