ZrO2(Y) ceramic with embedded particles of a pore-forming agent—ultrahigh molecular weight polyethylene—has been studied. It has been shown that the porosity of samples after sintering changed from 2...

WC/Y–TZP–Al₂O₃ hybrid ceramic–matrix composites (CMCs) with dispersed Hadfield steel particles were sintered and then tested at sliding speeds in the range of 7–37 m/s and contact pressure 5 MPa. Fast and low-temperature sinter-forging allowed obtaining micron-sized WC grains, submicron-sized alumina-reinforced yttria partially stabilized polycrystalline tetragonal zirconia (Y–TZP–Al₂O₃), and evenly distributed Hadfield steel grains. Such a microstructure provided new hybrid characteristics combining high hardness with high fracture toughness and tribological adaptation. The CMCs demonstrated low friction and high wear resistance that were better than those demonstrated by other composite materials such as, for example, MAX-phase composites, zirconia-base ceramics, ZrB₂-SiC ceramics, and metal matrix WC–(Fe–Mn–C) composites. These good tribological characteristics were obtained due to the in situ mechanochemical formation of iron tungstates FeWO₄ and Fe₂WO₆ on the worn surfaces of composite samples. These mixed oxides were included in multilayer subsurface structures that provided the self-lubricating and self-healing effects in high-speed sliding because of their easy shear and quasi-viscous behavior.