In the current work, the three-dimensional Navier-Stokes equations along with the energy and concentration equations for the fluid coupled with the energy and mass conservation equations for the solid (wood) are solved to study the transient heat and mass transfer during the heat treatment of wood. The model for wood is based on Luikov's approach and solves a set of coupled heat and mass transfer equations. The model equations are solved numerically for the temperature and moisture content histories under different treatment conditions. The simulation of the proposed conjugate problem allows the assessment of the effect of the heat and mass transfer within wood on the transfer in the adjacent gas, providing good insight on the complexity of the transfer mechanisms. To generate data for comparison, measurements of temperature and moisture content of wood samples in a thermogravimetric system were conducted under different operating conditions. It is shown that the predicted and measured values compared very favourably, implying that the proposed numerical algorithm can be used as a useful tool in designing high-temperature wood treatment processes.

Solidification of cryolite (Na3AlF6)-based bath takes place at different rates along the sideledge, and around alumina rafts and new anodes. The solidification rate has a significant impact on the structure and the chemical composition that determine the thermal conductivity and thus the thickness of sideledge, or the duration of the existence of the temporary frozen bath layers in other cases. Unfortunately, samples that can be collected in industrial cells are formed under unknown, spatially and temporally varying conditions. For this reason, frozen bath samples were created under different heat flux conditions in a well-controlled laboratory environment using the so-called cold finger technique. The samples were analyzed by X-ray Diffractometer (XRD) and Scanning Electron Microscope (SEM) in Back Scattering (BS) mode in order to obtain spatial distribution of chemical composition. Results were correlated with structural analysis. XRD confirmed our earlier hypothesis of recrystallization of cryolite to chiolite under medium heat flux regime. Lower α-alumina, and higher γ-alumina content in the samples obtained with very high heating rate suggest that fast cooling reduces α–γ conversion. In accordance with the expectation, SEM-BS revealed significant variation of the Na/Al ratio in the transient sample.