Research studies on Metal Organic Frameworks (MOF) based composites and their potential applications in environmental engineering and pollution control have recently emerged. An attractive material to form MOF composites is biochar (BC); a low-cost, highly porous carbonaceous by-product of biomass pyrolysis. This paper presents a critical review on MOF-biochar composites, focusing on fabrication, characterisation, modification, and applications in environmental protection and pollution control. The adsorption mechanisms and influential parameters are systematically examined to develop an insight into interactions between MOF and biochar in remedial process. The adsorption capacity of composites is generally doubled compared to the standalone biochar, while MOFs maintain their crystallinity, even over multiple regeneration cycles, indicating the composites' long-term applicability and sustainability. These findings highlight the potential of MOF-biochar composites for environmental applications and identify key areas for further research to enhance their sustainability in environmental protection and green energy.

Mechanistic understanding of thermo-osmosis at nano scale is linked with non-equilibrium thermodynamics of the phenomenon. Fluid molecules at the boundary layers of solid surfaces experience a driving force which generates thermo-osmotic flow.

Recent studies have highlighted the promising properties of metal-organic frameworks (MOF) and biochar composites as cost effective adsorbents. Although MOF-biochar composites have shown significant potential for contaminant removal in aquatic environments, further research is needed for their scalable performance in removing a wide range of emerging contaminants from wastewater. In this paper, we introduce a novel UiO67-biochar composite (MBC) for the first time, synthesised via an in-situ solvothermal method, as an innovative solution for removing heavy metals from water. The composite was characterised by various analytical techniques (SEM, TEM, XRD, FTIR, XPS, BET, and TGA) and the results demonstrated that the specific surface area of the composite (≈540 m²/g) elevated 28 times compared to the unmodified biochar (≈20 m²/g). The adsorption tests indicate remarkable adsorption capacity and removal efficiency in the range of 121.1 mg/g and 90.8 % as well as 59.7 mg/g and 89.5 % for Pb (II) and Cd (II), respectively, which sustained under impacts of co-existing ions. Kinetic studies demonstrated that the experimental data for both heavy metal ions were best described by the Pseudo-second order kinetic model, inferring that chemical interactions mainly control adsorption. The formulated material showed promising stability (retained crystallinity confirmed by XRD analysis) over reusability tests with approximately 87 % removal efficiency. The ion exchange, surface complexation, and electrostatic interactions were the main adsorption mechanisms of the heavy metal ions on the MBC composite. The formulated composite proposed in this study offers scalable, sustainable, and affordable material to treat heavy metal-polluted water and wastewater.

Despite a body of research carried out on thermally coupled processes in soils, understanding of thermo-osmosis phenomenon in clays and its effects on hydromechanical behavior is incomplete. This paper presents an investigation on the effects of thermo-osmosis on hydraulic behavior of saturated clays. A theoretical formulation for hydraulic behavior was developed, incorporating an explicit description of thermo-osmosis effects on coupled hydromechanical behavior. The extended formulation was implemented within a coupled numerical model for thermal, hydraulic, chemical, and mechanical behavior of soils. The model was tested and applied to simulate a soil heating experiment. It is shown that the inclusion of thermo-osmosis in the coupled thermohydraulic simulation of the case study provides a better agreement with the experimental data compared with the case in which only thermal expansion of the soil constituents was considered. A series of numerical simulations are also presented, studying the por...