Highlights The crystal facets featured with facet-dependent physical and chemical properties can exhibit varied electrocatalytic activity toward hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) attributed to their anisotropy. The highly active exposed crystal facets enable increased mass activity of active sites, lower reaction energy barriers, and enhanced catalytic reaction rates for HER and OER. The formation mechanism and control strategy of the crystal facet, significant contributions as well as challenges and perspectives of facet-engineered catalysts for HER and OER are provided.

A green, versatile, and universal H₂O₂ activation method is proposed to improve the capacitive properties of high-mass loading wood-based supercapacitors.

Porous carbon nanomaterials (PCNs) are widely applied in energy storage devices. Traditionally, PCNs were mainly synthesized by activation and templating methods, which are time-consuming, tedious, corrosive and relatively high cost. Therefore, the development of easier and greener methods to produce PCNs is of great significance. Recently, organic potassium salts (OPSs) emerged as versatile reagents for synthesizing PCNs. The OPS-based synthesis of PCNs can avoid the use of large amounts of corrosive chemical agents. Potassium carbonate generated in situ from the decomposition of OPSs could serve as both a green activation agent and a water-removable template to produce nanopores. Potassium oxide and potassium formed at higher temperature could generate additional porosity, contributing to a highly porous architecture. The carbon-rich organic moiety could function as a carbon precursor and chemical blowing agent. This review aims to elucidate the multifunctionality of OPSs in the synthesis of PCNs and the capacitive performance of the corresponding PCNs. To this end, recent progress on the capacitive performance of PCNs synthesized from OPSs is summarized. This review provides constructive viewpoints for the cost-effective and green synthesis of PCNs with the aid of OPSs for application in supercapacitors.

A summary of synthetic strategies, catalytic performance, current challenges, and future prospects is provided for nanoarray catalysts constructed on free-standing carbon substrates for the oxygen evolution reaction (OER).