Continental red beds, widely formed at various geologic timescales, are sedimentary rocks and sediments with red as the main color. Geoscientists have analyzed the geomorphology, paleomagnetism, paleoenvironments, paleontology, energy, and minerals in continental red beds. Despite the agreement that fine-grained hematite is closely related to the color of continental red beds, controversies and problems still exist regarding the micro-mechanism of their formation. As a review, this paper details the composition and color properties of pigmentation in red beds, analyzes the existence and distribution of authigenic hematite, and summarizes the iron sources and the formation of hematite. In addition, we introduce the fading phenomenon observed in continental red beds, including three types of secondary reduction zones: reduction spots, reduction strips, and reduction areas. Lastly, this paper summarizes the evolution of color in continental red beds, emphasizes the relationship between authigenic hematite and the diagenetic environment, and proposes possible research directions for future red bed-related issues.
Sedimentary facies color is an important paleoclimate indicator, but may be unreliable in thick continental red beds. The Danxia Formation is the landscape strata of the Danxia basin, and its color fluctuates between reddish-brown and reddish-purple vertically. This study examined the ferric oxides characteristics, distribution, and mineral composition of the Danxia Formation using a variety of analytical techniques, including optical microscopy, high-resolution scanning electron microscopy, electron probe microanalysis, X-ray diffraction, and micro-Raman spectroscopy. The results indicate that the reddish-brown mineral is composed primarily of fine hematite with traces of goethite, while the reddish-purple mineral consists solely of fine hematite. These hematites exhibit a particle size range of submicron to micron and display various morphologies, including spherical, flake, and fibrous forms. Goethite particles are needle-shaped and often form star-shaped aggregates containing twins. Whole rock geochemical analysis reveals a strong positive correlation between iron and iron group elements, as well as phosphorus and rare earth elements. The findings suggest that the reddening of the Danxia Formation occurs during diagenesis, with fine hematite forming as a result of the alteration of iron-bearing detrital grains. In addition, vertical color variations in Danxia Formation are not attributable to the paleoclimate records, but rather the result of the differentiation of sediment sources. This study provides a novel viewpoint for examining the coloration of thick continental red beds in other regions.
CM chondrite is the most important carbonaceous chondrite containing abundant Ca, Al-rich inclusions (CAIs) and other interesting objects, which probably experienced early condensation processes in the Solar Nebula environment and later alteration in parent body surroundings. Thus, it is a vital raw material to explore in the formation and evolution of the early Solar System. Grove Mountains (GRV) CM chondrites have been collected from Antarctica by Chinese Antarctic Research Expedition (CARE) for nearly 20 years. In this paper, we review the study of GRV CM chondrites. In total, there are eight CM chondrites named Grove Mountains officially approved by the Meteoritical Society. Petrology and mineral, matrix, CAIs, metal and sulfide in GRV CM chondrites are carefully reviewed. All the meteorites have similar characteristics with a dominant component of matrix. Phyllosilicate minerals generally developed in the matrix. The different altered mineral assemblages, contents and chemical compositions show that these chondrites underwent varying degrees of aqueous alteration, of which GRV 020005 is the most heavily altered CM chondrite. GRV 020025 is the second heaviest of the CM samples with the most extensive studies among these chondrites. It contains abundant CAIs and amoeboid olivine aggregates (AOAs). The modal content is about 1.0 vol% for CAIs. The findings of some new types of CAIs (such as hibonite-rich and spinel-pyroxene inclusions with forsterite-rich accretionary rims), AOAs and a complex, fine-grained P-bearing sulfide phase enrich the study of GRV 020025.
This study investigates the Danxia Basin, the place where Danxia landforms were first named, by employing diffuse reflectance spectroscopy to analyze samples from various hue sequences of red beds. The colors of the Danxia red beds were precisely and quantitatively analyzed using the CIE color space and the Munsell color system. The raw spectra of the samples were then transformed using the second derivative of the Kubelka–Munk function and continuum removal techniques to perform spectral analysis, aiming to elucidate the absorption characteristics of Fe oxides and their influence on the coloration of the Danxia red beds. The results show that the Munsell hues of the Danxia red beds span from 6.5R to 9YR, while powdered samples exhibit a slight yellow shift, ranging from 2.5YR to 0.1Y, with increased chroma and significantly higher lightness. Fe oxides display three main absorption bands in the visible spectrum: (4E; 4A1) ← 6A1, 4T2 ← 6A1, and 2(4T1) ← 2(6A1) (EPT). Among these, the EPT band plays a pivotal role in determining the color. Since the Fe oxides in the Danxia red beds are predominantly composed of hematite with minor goethite, the EPT (Hem) absorption band is the most prominent, occurring between 526 and 544 nm. While the CIE color space offers superior precision for color measurement and analysis, the Munsell system provides ease of description. Therefore, a combination of both systems is recommended for practical applications.