The Zaozigou Au-Sb deposit has been controversial in its genesis and remains one of the most difficult ore systems to fully understand in West Qinling. The mineralization shows a broad spatial association with Triassic dikes and sills, which were previously thought to be genetically related to mineralization. Our U-Pb zircon dating in this contribution indicates that the ore-hosting porphyritic dacites were formed at 246.1 ± 5.2 Ma and 248.1 ± 3.8 Ma. The magmatic zircons yield εHf(t) values ranging from −12.5 to −8.9, with corresponding two-stage model ages of 2.08 to 1.83 Ga. The magma therefore could be derived from partial melting of Paleoproterozoic crustal materials. The ore-hosting porphyritic dacites have low oxygen fugacity, with ΔFMQ ranging from −4.61 to −2.56, indicating that magmas could have been sulfide-saturated during evolution in deep chambers and precluding the possibility that metals were released from the melt. Zaozigou exhibits characteristics widespread volcanics, massive sulfide mineralization, rare reduced mineral assemblage and discrete alteration zones which are not typical of reduced intrusion-related or porphyry gold systems. We propose that the spatially-related Triassic porphyritic dacite and dike swarm is not genetically related to the ore formation of Zaozigou Au-Sb deposit.
Determining absolute ages of orogenic faults is critical to understanding the deformation process in the upper crust, but obtaining age remains a problem due to the lack of readily available techniques. Carbonates occur as veins in faults in a range of geological settings, and thus it is a suitable mineral for U-Pb geochronology. Here, we apply the new approach of U-Pb dating on syn-tectonic dolomite veins from the Gelouang gold deposit in the western Qinling Orogen to unravel the absolute timing of the fault formation shedding new light on the regional upper crustal deformation archive. In situ LA-ICP-MS U-Pb dating of dolomite yielding a successful age of 115–112 Ma demonstrates that the dolomite precipitated coeval with tectonic events ascribed to the post-orogenic deformation phase in the Qinling Orogen. This event is possibly correlated with broader intracontinental processes and might be an inevitable response to the extensional deformation of the Qinling Orogen. The presented LA-ICP-MS dolomite U-Pb age successfully represents the age of a specific structure that encompasses the intracontinental process in the Qinling Orogen. Moreover, it demonstrates the utility of the method to decipher a response to complex deformation histories on a regional scale.