The Zaozigou Au-Sb deposit has been controversial in its genesis and remains one of the most difficult ore systems to fully understand in West Qinling. The mineralization shows a broad spatial association with Triassic dikes and sills, which were previously thought to be genetically related to mineralization. Our U-Pb zircon dating in this contribution indicates that the ore-hosting porphyritic dacites were formed at 246.1 ± 5.2 Ma and 248.1 ± 3.8 Ma. The magmatic zircons yield ε_Hf(t) values ranging from −12.5 to −8.9, with corresponding two-stage model ages of 2.08 to 1.83 Ga. The magma therefore could be derived from partial melting of Paleoproterozoic crustal materials. The ore-hosting porphyritic dacites have low oxygen fugacity, with ΔFMQ ranging from −4.61 to −2.56, indicating that magmas could have been sulfide-saturated during evolution in deep chambers and precluding the possibility that metals were released from the melt. Zaozigou exhibits characteristics widespread volcanics, massive sulfide mineralization, rare reduced mineral assemblage and discrete alteration zones which are not typical of reduced intrusion-related or porphyry gold systems. We propose that the spatially-related Triassic porphyritic dacite and dike swarm is not genetically related to the ore formation of Zaozigou Au-Sb deposit.

Crustal delamination induced by eclogitization of orogenic roots, in addition to plate subduction, is an important process that transfers crustal materials back into the mantle. Many previous studies have demonstrated a causal link between crustal delamination and eclogitization, but actual magmatic records of the process are rarely documented. Here we present detailed studies on two distinct late Paleozoic adakite suites in the Awulale Mountains (Chinese Western Tianshan), that is, the suites with high (HN) and low (LN) Nb/Ta ratios, to constrain the regional crustal delamination. Both igneous suites have adakitic affinity and formed by partial melting of the juvenile thickened lower crust with different residual mineral assemblages in their source regions. The late Carboniferous HN adakite has superchondritic Nb/Ta (21.4–23.3) and high Dy/Yb (2.66–2.88) ratios and may have formed via rutile‐bearing, eclogite‐controlled melting of the lower crust, implying crustal thickening and eclogitization. In contrast, the Permian LN adakites have varying and lower ranges of Nb/Ta (12.9–20.0) and Dy/Yb ratios (1.35–2.53), which were probably derived from mixing of garnet‐bearing amphibolite with minor rutile‐bearing, eclogite‐controlled melts, implying crustal thinning and the end of eclogitization. The succession of these two adakite suites suggests that during the late Carboniferous to early Permian, eclogitization of the orogenic root, accompanying successive crustal delaminations, occurred in this region. Accordingly, our results imply that adakites with different geochemical features are potential tracers for the mineralogy of orogenic roots and, importantly, provide convincing evidence for eclogitization‐induced crustal delamination in orogenic belts.

Exploitable or potentially exploitable deposits of critical metals, such as rare-earth (REE) and high-field-strength elements (HFSE), are commonly associated with alkaline or peralkaline igneous rocks. However, the origin, transport and concentration of these metals in peralkaline systems remains poorly understood. This study presents the results of a mineralogical and geochemical investigation of the Na-metasomatism of alkali amphiboles and clinopyroxenes from a barren peralkaline granite pluton in NE China, to assess the remobilization and redistribution of REE and HFSE during magmatic-hydrothermal evolution. Alkali amphiboles and aegirine-augites from the peralkaline granites show evolutionary trends from sodic-calcic to sodic compositions, with increasing REE and HFSE concentrations as a function of increasing Na-index [Na^#, defined as molar Na/(Na+Ca) ratios]. The Na-amphiboles (i.e., arfvedsonite) and aegirine-augites can be subsequently altered, or breakdown, to form hydrothermal aegirine during late- or post-magmatic alteration. Representative compositions analyzed by in-situ LA-ICPMS show that the primary aegirine-augites have high and variable REE (2194–3627 ppm) and HFSE (4194–16,862 ppm) contents, suggesting that these critical metals can be scavenged by alkali amphiboles and aegirine-augites. Compared to the primary aegirine-augites, the presentative early replacement aegirine (Aeg-I, Na^# = 0.91–0.94) has notably lower REE (1484–1972) and HFSE (4351–5621) contents. In contrast, the late hydrothermal aegirine (Aeg-II, Na^# = 0.92–0.96) has significantly lower REE (317–456 ppm) and HFSE (6.44–72.2 ppm) contents. Given that the increasing Na^# from aegirine-augites to hydrothermal aegirines likely resulted from Na-metasomatism, a scavenging-release model can explain the remobilization of REE and HFSE in peralkaline granitic systems. The scavenging and release of REE and HFSE by Na-metasomatism provides key insights into the genesis of globally significant REE and HFSE deposits. The high Na-index of the hydrothermal aegirine might be useful as a geochemical indicator in the exploration for these critical-metals.