The power conversion efficiencies (PCEs) of metal-oxide-based regular perovskite solar cells have been higher than 25% for more than 2 years. Up to now, the PCEs of polymer-based inverted perovskite solar cells are widely lower than 23%. PEDOT:PSS thin films, modified PTAA thin films and P3CT thin films are widely used as the hole transport layer or hole modification layer of the highlyefficient inverted perovskite solar cells. Compared with regular perovskite solar cells, polymer-based inverted perovskite solar cells can be fabricated under relatively low temperatures. However, the intrinsic characteristics of carrier transportation in the two types of solar cells are different, which limits the photovoltaic performance of inverted perovskite solar cells. Thanks to the low activation energies for the formation of high-quality perovskite crystalline thin films, it is possible to manipulate the optoelectronic properties by controlling the crystal orientation with the different polymer-modified ITO/glass substrates. To achieve the higher PCE, the effects of polymer-modified ITO/glass substrates on the optoelectronic properties and the formation of perovskite crystalline thin films have to be completely understood simultaneously.

The power conversion efficiency (PCE) of single-junction solar cells was theoretically predicted to be limited by the Shockley–Queisser limit due to the intrinsic potential loss of the photo-excited electrons in the light absorbing materials. Up to now, the optimized GaAs solar cell has the highest PCE of 29.1%, which is close to the theoretical limit of ~33%. To pursue the perfect photovoltaic performance, it is necessary to extend the lifetimes of the photo-excited carriers (hot electrons and hot holes) and to collect the hot carriers without potential loss. Thanks to the long-lived hot carriers in perovskite crystal materials, it is possible to completely convert the photon energy to electrical power when the hot electrons and hot holes can freely transport in the quantized energy levels of the electron transport layer and hole transport layer, respectively. In order to achieve the ideal PCE, the interactions between photo-excited carriers and phonons in perovskite solar cells has to be completely understood.

Buttcoupling is the most efficient way to excite surface plasmon polariton (SPP) waves at dielectric/metal interfaces in order to realize applications in broadband and ultra-compact integrated circuits (IOCs). We propose a reasonable waveguide structure to efficiently excite and collect the SPP waves supported in a plasmonic trench waveguide in the long-haul telecommunication wavelength range. Our simulation results show that the coupling efficiency between the dielectric strip waveguides and a plasmonic trench waveguide can be optimized, which is dominated by the zigzag propagation path length in the dielectric strip loaded on the metal substrate. It is noted that nearly a 100% coupling efficiency can be achieved when the distance between the excitation source and the plasmonic waveguide is about 6.76 μm.

The conformal loading effects of P3CT-Na polymers on ITO/glass samples were investigated using different concentrations of P3TC-Na/water solution, which significantly influenced the device efficiency of the resultant inverted perovskite solar cells. The obtained water-droplet contact angle images, surface morphological images, photoluminescence spectra and X-ray diffraction patterns show that the hydrophilic moiety of the P3CT-Na polymers plays an important role in the conformal loading effects, thereby resulting in a smoother perovskite crystalline film due to the formation of merged grains. It is noted that the average power conversion efficiency increases from 14.83% to 17.27% with a decrease in the concentration of the P3CT-Na/water solution from 60 wt% to 48 wt%.

Coupled metallic-wedge nano-plasmonic (CWP) waveguides were predicted as the best building blocks, which can realize ultra-compact and broadband integrated optical circuits (IOCs) due to the localized near-field distributions at the dielectric/metal interfaces. Our simulation results show that the manipulations of the near-field distribution and the near-field modal coupling in CWP waveguides can effectively minimize the power loss by varying the wedge angles, which can avoid the loss from the metallic structure and thereby improving the practical application in IOCs.