Geopolymers can be used as a thermally insulated material because of their considerable porosity, whereas the combined effect of various modifying agents on their heat-insulating properties remains unexplored. Here, orthogonal experiments were carried out to evaluate the thermal insulation performance of fly ash geopolymer modified by phenolic resin, silica aerogel, and hydrogen peroxide. Moreover, variance analysis and range analysis were applied to estimate the influence of modifying agents on the thermal insulation performance of the geopolymer. The results demonstrate that the thermal conductivity of fly ash geopolymer significantly reduces (from 0.48 W/m·K to 0.12 W/m·K) due to the combined effect of the three modifying agents. Based on the variance analysis and range analysis, the optimum thermal conductivity ultimately reaches 0.08 W/m·K via a best composition scheme of the three modifying agents. Moreover, phenolic resin can facilitate the formation of a network structure and increase the porosity of micron pores (>1 μm). Hydrogen peroxide can be decomposed into O₂ in an alkaline environment and leave large-diameter pores (>1 μm) during curing. Some silica aerogel is embedded in the geopolymer matrix as microspheres with extremely low thermal conductivity, whereas the rest of the silica aerogel may react with the alkali activator to form water, and subsequently leaves pores (>1 μm) after evaporation of water during the curing. In addition, a newly modified Maxwell–Euchen model using iterative calculation and considering the Knudsen effect (pores of micron or even nanometer scale) is proposed and validated by the experimental data. The foamed geopolymer in this research can be used as a reference for building insulation layer design. This research unravels phenolic resin-, silica aerogel-, and hydrogen peroxide-influenced thermal insulation mechanisms of geopolymer that may have impacts on deployment of a thermally insulating material in the construction field.

Seasonally frozen ground regions occupy approximately 55% of the exposed land surface in the Northern Hemisphere, and frost heave is the common global problem in seasonally frozen soil areas. Frost heave induces uneven deformation of ground and damages railways, road paving, and buildings. How to mitigate frost heave is the most important technical issue in this field that has provoked great interest. Here, using freezing experiments, we investigate the effect of anionic polyacrylamide (APAM) polymer on frost susceptible soil. The results demonstrate a so-far undocumented inhibition of frost heave by APAM in freezing soil, namely APAM (tested at concentrations from 0.0 wt% to 0.60 wt%) slows down the frost heave by a factor of up to 2.1 (since 0.60 wt% APAM can decrease frost heave from 8.56 mm to 4.14 mm in comparison to the control experiment). Moreover, it can be observed that the maximum water content near the frozen fringe decreased from 53.4% to 31.4% as the APAM content increased from 0.0 wt% to 0.60 wt%, implying a mitigated ice lens growth. Hydrogen bonding between APAM and soil particles triggers an adsorption mechanism that accumulates soil particles, and thus can potentially inhibit the separation and growth of the ice lens. Moreover, the residue of APAM due to hydrogen bonding-induced adsorption in the pores of granular media may narrow seepage channels (capillary barriers) and provide an unfavourable condition for water migration. The use of APAM can also increase the viscosity of the solution, which causes a greater water migration resistance. This research provides new insights into APAM-influenced frost heave (introducing APAM into the soil can induce bridging adsorption between APAM polymer segments and a particle surface), can enable engineers and researchers to utilise chemical improvement design and to consider suitable actions (e.g., by injecting APAM solution into a frost susceptible soil or using APAM-modified soil to replace the frost susceptible soil) to prevent frost heave from having a negative impact on traffic roads and buildings in cold regions.

An oscillating heat pipe (OHP) is an effective heat transfer device for the thermal management of electronic devices. However, the heat transfer mechanism of the OHP was not fully understood due to its complicated operation characteristics. In this paper, the thermal performance of an OHP was experimentally studied. The condensation and evaporation temperature variations were monitored under different heat inputs and were then used to evaluate the OHP system operating characteristics. Thermal resistance was used as a key parameter to evaluate the thermal performance of the OHP system. The results indicated that as the heat input increased from 25 to 100 W, the average thermal resistance decreased while the stable evaporating and condensing temperatures increased. The equivalent heat transfer coefficient was derived theoretically. It showed that the reciprocal of the radial heat transfer coefficient increased with increasing liquid film thickness. Based on this result, an empirical correlation was proposed to evaluate the thermal resistance of an OHP system. This correlation was validated using both the experimental data provided in this study and the data collected from the open literature. The comparison results indicated that the proposed empirical correlation could reasonably predict the thermal resistance under different filling ratios and heat inputs.

This study investigates the effects of different sealing materials, steel lining and Fiber-Reinforced Polymer (FRP), on the thermodynamic properties of hydrogen storage in lining rock caverns (LRCs). A thermodynamic coupling equation for hydrogen storage in LRCs was developed, and its validity was confirmed by comparison with simulations and data from the Huntorf power station. The leakage rate, temperature changes, and stress distribution of steel and FRP sealing layers with varying thicknesses were analyzed over a 30-day period. The results show that the leakage rate of the FRP layer decreases significantly with thickness, with a peak leakage of 1.3 g/s for the 10 mm layer, stabilizing at around 0.1 g/s for the 100 mm layer. Temperature fluctuations within the cavern are periodic, with more pronounced changes in the FRP layer as its thickness increases. Steel lining experiences minimal temperature changes. Additionally, increasing the FRP thickness results in larger fluctuations in the principal stress of both the sealing and lining layers, impacting the surrounding rock mass. The FRP lining experiences higher tensile stress, while the steel lining shows smaller changes. A thicker FRP layer also increases normal and shear stresses in the surrounding rock, potentially affecting cavern stability. These findings emphasize the importance of selecting appropriate sealing materials and thicknesses to improve the efficiency and stability of hydrogen storage systems.

In this paper, a finite element numerical model of thermal-hydro-mechanical of energy piles under multi-layer geological conditions was established, and field tests of ultra-long energy pile (1000-mm-diameter, 44-m-long) were carried out to reveal the temperature distribution and mechanical properties of energy pile under typical working conditions. Based on the analytical results, a softening shear model of the energy–soil interface under the condition of large shear displacement was proposed with the load transfer method, and the reliability of the model was verified. The model can simulate the shear–displacement relationship of the pile–soil interface under different geological conditions.

The underground energy geostructure represented by the energy pile is one of the key paths for the cooperative development of underground space and geothermal energy. Because of its advantages of low cost, high efficiency and no extra occupation of underground space, it has become a feasible alternative to the borehole heat exchanger. The change in the temperature field of the energy pile and its surrounding ground not only affects the geological environment but also influences the thermomechanical performance and the durability of the structure. However, the temporal and spatial unsteady-state temperature distribution of piles and surrounding rock under typical intermittent and unbalanced thermal load conditions is still unclear. In this paper, a finite element model was applied to analyze the unsteady-state temperature distribution, and the thermomechanical behavior of the energy pile group was developed and verified. The temperature field distribution of pile and surrounding rock under typical intermittent working and unbalanced thermal load conditions were determined. Moreover, the thermomechanical behavior characteristics of the energy pile group were investigated. Finally, the influences of pile layout on the thermomechanical behavior of the energy pile group were identified by designing six different scenarios. The results indicate that under typical intermittent operation conditions, the temperature of the energy pile and surrounding ground near the heat exchange pipe varies periodically. For areas with unbalanced cooling and heating loads, long-term operation of energy piles leads to thermal accumulation, and the maximum temperature of energy piles occurs in the first daily cycle. In summer/winter working conditions, the increase/decrease in pile temperature induces axial compression/tensile stress. When the pile group is partially used as the energy pile, the non-energy pile acts as the “anchor pile”, and it generates the added tensile stress.