Cellulose is one of the most abundant natural polymers with excellent biocompatibility, non-toxicity, flexibility, and renewable source. Regenerated cellulose (RC) products result from the dissolution-regeneration process risen from solvent and anti-solvent reagents, respectively. The regeneration process changes the cellulose chain conformation from cellulose I to cellulose II, leads the structure to have more amorphous regions with improved crystallinity, and inclines towards extensive modification on the RC products such as hydrogel, aerogel, cryogel, xerogel, fibers, membrane, and thin film. Recently, RC products are accentuated to be used in the agriculture field to develop future sustainable agriculture as alternatives to conventional agriculture systems. However, different solvent types and production techniques have great influences on the end properties of RC products. Besides, the fabrication of RC products from solely RC lacks excellent mechanical characteristics. Thus, the flexibility of RC has allowed it to be homogenously blended with other materials to enhance the final products’ properties. This review will summarize the properties and preparation of potential RC-based products that reflect its application to replace soil the plantation medium, govern the release of the fertilizer, provide protection on crops and act as biosensors.
Urban agriculture plays a vital role in ensuring the self-sufficiency of a great variety of fresh vegetables and nutrients. It promotes a sustainable food system as well as reducing the dependency on imports for the growing population. Urban farming has made it possible for agriculture practices to be implemented anywhere at any time in a sophisticated way. Hydrogel has been introduced in urban agriculture in the past few decades. However, the application of hydrogel in urban agriculture is still being explored in terms of hydrogel types, structure, physical and chemical properties, change due to external factors, and its suitability for different plant species. This review discusses the potentials and limitations of hydrogel in different application conditions. We present the state of knowledge on hydrogel production and crosslinking methods, hydrogel characteristics, water absorption and release mechanisms of hydrogel, hydrogel advantages and limitations, and current and future applications in urban farming.
Development of polyurethane foam (PUF) containing bio-based components is a complex process that requires extensive studies. This work reports on the production of rigid PUFs from polyol obtained via liquefaction of oil palm empty fruit bunch (EFB) biomass with different isocyanate (NCO) indexes. The effect of the NCO index on the physical, chemical and compressive properties of the liquefied EFB-based PUF (EFBPUF) was evaluated. The EFBPUFs showed a unique set of properties at each NCO index. Foaming properties had affected the apparent density and cellular morphology of the EFBPUFs. Increasing NCO index had increased the crosslink density and dimensional stability of the EFBPUFs via formation of isocyanurates, which had also increased their thermal stability. Combination of both foaming properties and crosslink density of the EFBPUFs had influenced their respective compressive properties. The EFBPUF produced at the NCO index of 120 showed the optimum compressive strength and released the least toxic hydrogen cyanide (HCN) gas under thermal degradation. The normalized compressive strength of the EFBPUF at the NCO index of 120 is also comparable with the strength of the PUF produced using petrochemical polyol.
Hybrid glass fibre reinforced polymer (GFRP) composites have been used for decades in various engineering applications. However, it has a drawback with its application in marine/flood environments due to a lack of water resistance and frail mechanical stability. Floods have been considered one of the most periodic hazards that could hit urban areas, due to climate change. The present paper aims to address this gap and to investigate the mechanical properties (tensile, compressive, and flexural strength) and water absorption capacity of hybrid GFRP composite comprising woven E-glass fabric and epoxy resin, various reinforcing materials (kenaf and coconut fibres), and various filler materials (fly ash, nano-silica, and calcium carbonate (CaCO3). The composites with 30 wt.% GFRP, 50 wt.% resin, 15 wt.% fly ash, 5 wt.% CaCO3, 10 wt.% GFRP, 60 wt.% resin, and 30 wt.% fly ash showed the lowest water absorption property of 0.45%. The results revealed that the GFRP composite reinforced kenaf fibres with nano-silica, fly ash, and CaCO3 improved the water absorption resistance. At the same time, GFRP reinforced the coconut fibres with fly ash, and kenaf fibres with CaCO3 showed no favourable impact on water absorption. The identification of a hybrid GFRP composite with various reinforcing materials and fillers would assist future developments with a more compatible, enhanced, and reliable water-resistant composite, specifically for structural applications in flood-prone areas.
18 September 2023 in International Journal of Biological Macromolecules