Chitosan and its derivatives are widely used in food packaging, pharmaceutical, biotechnology, medical, textile, paper, agriculture, and environmental industries. However, the flexibility of chitosan films is extremely poor, which limits its relevant applications to a large extent. In this paper, chitosan/sorbitol/nano-silica (CS/sorbitol/SiO₂) composite films were prepared by the casting film method using chitosan, sorbitol, Tween-80 and nano-SiO₂ as raw materials. The structure of the films was characterized by infrared spectroscopy, electron scanning microscopy, and X-ray diffraction analysis. The effects of sorbitol and nano-silica dosage on the mechanical properties, thermal properties and water vapor barrier properties of the composite film were investigated. The results show that with the gradual increase in sorbitol (≤75 wt %), the elongation at the break of chitosan/sorbitol films significantly increased. When the addition of sorbitol was 75 wt %, the elongation at break of the chitosan/sorbitol composite film was 13 times higher than that of the chitosan film. Moreover, nano-SiO₂ can further improve the mechanical properties and thermal stability of the chitosan/sorbitol composite films. When the amount of nano-silica was 4.5 wt %, the composite film became more flexible, with a maximum elongation of 90.8% (which is 14 times that of chitosan film), and its toughness increased to 10.52 MJm⁻³ (which is 6 times that of chitosan film). This study balances the tensile strength and elongation at break of the composite films by adding a plasticizer and nano-filler, providing a reference for the preparation of chitosan composites or their blending with other polymers, and has practical guiding significance for the industrial production of biomass plastics.

A ZrSi₂-SiC/SiC gradient coating system was designed to reduce the thermal stress of anti-oxidation coatings for C/C composites and prolong their anti-oxidation time at a high temperature. The SiC transition layer was prepared by pack cementation and the gradient ZrSi₂-SiC outer coatings with different ZrSi₂ contents added were deposited by supersonic air plasma spraying (SAPS). The micro-morphologies and phase compositions of the coatings were studied by SEM, EDS, XRD, and TG/DSC, and their anti-oxidation performances were tested by a static oxidation experiment. The findings suggested that the gradient coating with 30 wt.% ZrSi₂ content displayed the optimum and dense microstructure without obvious pores and microcracks, compared with the other three proportional coatings. During the oxidation test, because of the oxidation reaction of ZrSi₂ and SiC phases, a large amount of silica was formed in the coating to fill the pores and microcracks and densify the coating further. Oxidation products ZrO₂ and ZrSiO₄, having a high melting point and outstanding anti-oxidation property, were embedded in the SiO₂ glass layer to reduce the layer volatilization rate and improve the ability to block oxygen. Therefore, the specimen with 30 wt.% ZrSi₂ still kept mass gain after 188 h oxidation time at 1500 °C. However, when the oxidation time was increased to 198 h, it had a mass loss of 0.1%, because the coating compactness was destroyed by the escape of the oxidation gases.

In order to further improve the oxidation resistance of SiC-coated C/C composites used in extreme environments, TaSi₂ coatings were deposited on the surfaces of SiC-coated C/C composites by supersonic air plasma spraying (SAPS) with different spraying power parameters, under other fixed parameter (gas flow, power feed rate, spraying distance and nozzle diameter) conditions. The micro-structures and phase characteristics of the TaSi₂ coatings prepared with the four kinds of spraying powers (40 kW, 45 kW, 50 kW and 55 kW) were analyzed. Also, the inter-facial bonding strengths and fracture modes between the four TaSi₂ coatings and the SiC coating were studied. The results showed that with an increase in the spraying power, the morphologies of the TaSi₂ coatings appeared from loose to dense to loose. When the spraying power was 50 kW, the deposition rate reached a maximum of 39.8%. The TaSi₂ coating presented an excellent micro-structure without obvious pores and microcracks, and its inter-facial bonding strength was 15.3 ± 2.3 N. Meanwhile, the fracture surface of the sample exhibited a brittle characteristic.