Wood is a natural renewable material with a porous structure widely used in construction, furniture, and interior decoration, yet its intrinsic flammability poses safety risks. Therefore, environmentally friendly flame retardants have received increasing attention. In this study, a water-soluble flame retardant, consisting of bio-resourced phytic acid (PA), hydrolyzed collagen (HC), and glycerol (GL), was used to improve the flame retardancy of wood (“PHG/wood”) through full cell vacuum-pressure impregnation. Morphology and Fourier transform infrared analysis results show that the flame retardant impregnated the wood and adhered evenly to the wood vessels. A PA/HC/GL ratio of 3:1:1 (concentration of the flame retardant solution = 30%) maximized the limiting oxygen index (LOI, 41%) and weight gain (51.32%) for PHG-C30/wood. The flame retardant formed an expansive layer after heating, and the treated wood showed an improved combustion safety performance such that the fire performance index and residue of PHG-C30/wood were 75 and 126.8% higher compared with that of untreated wood, respectively. The peak and total heat release were also significantly reduced by 54.7 and 47.7%, respectively. The PHG/wood exhibited good carbon-forming performance and a high degree of graphitization after combustion. The dense carbon layer provides condensed phase protective action, and non-combustible volatile gases, such as H₂O, CO₂, and NH₃, are released simultaneously to dilute the fuel load in the gas phase. Thus, PHG is shown to be an effective flame retardant for wood.

Particle boards are manufactured through a hot pressing process using wood materials (natural polymer materials) and adhesive, which find common usage in indoor decorative finishing materials. Flame-retardant particleboard, crucial for fire safety in such applications, undergoes performance analysis that includes assessing temperature distribution across its facing surface and temperature increase on the backside surface during facade combustion, yielding critical insights into fire scenario development. In this study, a compact flame spread apparatus is utilized to examine the flame retardancy and combustion behavior of particle boards, with a specific emphasis on the application of cost-effective flame retardants, encompassing aluminum hypophosphite (ALHP), an intumescent flame retardant (IFR) comprising ammonium polyphosphate (APP), melamine (MEL), and Dipentaerythritol (DPE), alongside magnesium hydroxide (MDH), and their associated combustion characteristics. The D_300°C values, representing the vertical distance from the ignition point (IP) to P_300°C (the temperature point at 300 °C farthest from IP), are measured using a compact temperature distribution measurement platform. For MDH/PB, APP + MEL + DPE/PB, and ALHP/PB samples, the respective D_300°C values of 145.79 mm, 117.81 mm, and 118.57 mm indicate reductions of 11.11%, 28.17%, and 27.71%, compared to the untreated sample’s value of 164.02 mm. The particle boards treated with ALHP, IFR, and MDH demonstrated distinct flame-retardant mechanisms. MDH/PB relied on the thermal decomposition of MDH to produce MgO and H₂O for flame retardancy, while APP + MEL + DPE/PB achieved flame retardancy through a cross-linked structure with char expansion, polyphosphate, and pyrophosphate during combustion. On the other hand, ALHP/PB attained flame retardancy by reacting with wood materials and adhesives, forming a stable condensed P-N-C structure. This study serves as a performance reference for the production of cost-effective flame-resistant particleboards and offers a practical method for assessing its fire-resistant properties when used as a decorative finishing material on facades in real fire situations.