According to the laws of thermodynamics, no heat engine can beat the efficiency of a Carnot cycle. This efficiency traditionally comes with vanishing power output and practical designs, optimized for power, generally achieve far less. Recently, various strategies to obtain Carnot’s efficiency at large power were proposed. However, a thermodynamic uncertainty relation implies that steady-state heat engines can operate in this regime only at the cost of large fluctuations that render them immensely unreliable. Here, we demonstrate that this unfortunate trade-off can be overcome by designs operating cyclically under quasistatic conditions. The experimentally relevant yet exactly solvable model of an overdamped Brownian heat engine is used to illustrate the formal result. Our study highlights that work in cyclic heat engines and that in quasistatic ones are different stochastic processes.
1 July 2016 in Journal of Statistical Mechanics: Theory and Experiment
We investigate maximum efficiency at a given power for low-dissipation heat engines. Close to maximum power, the maximum gain in efficiency scales as a square root of relative loss in power and this scaling is universal for a broad class of systems. For low-dissipation engines, we calculate the maximum gain in efficiency for an arbitrary fixed power. We show that engines working close to maximum power can operate at considerably larger efficiency compared to the efficiency at maximum power. Furthermore, we introduce universal bounds on maximum efficiency at a given power for low-dissipation heat engines. These bounds represent direct generalization of the bounds on efficiency at maximum power obtained by Esposito et al (2010 Phys. Rev. Lett . 105 150603). We derive the bounds analytically in the regime close to maximum power and for small power values. For the intermediate regime we present strong numerical evidence for the validity of the bounds.
A universality in optimization of trade-off between power and efficiency for low-dissipation Carnot cycles is presented. It is shown that any trade-off measure expressible in terms of efficiency and the ratio of power to its maximum value can be optimized independently of most details of the dynamics and of the coupling to thermal reservoirs. The result is demonstrated on two specific trade-off measures. The first one is designed for finding optimal efficiency for a given output power and clearly reveals diseconomy of engines working at maximum power. As the second example we derive universal lower and upper bounds on the efficiency at maximum trade-off given by the product of power and efficiency. The results are illustrated on a model of a diffusion-based heat engine. Such engines operate in the low-dissipation regime given that the used driving minimizes the work dissipated during the isothermal branches. The peculiarities of the corresponding optimization procedure are reviewed and thoroughly discussed.
We investigate fluctuations of output work for a class of Stirling heat engines with working fluid composed of interacting units and compare these fluctuations to an average work output. In particular, we focus on engine performance close to a critical point where Carnot's efficiency may be attained at a finite power as reported by M. Campisi and R. Fazio [ Nat. Commun. 7, 11895 (2016)]. We show that the variance of work output per cycle scales with the same critical exponent as the heat capacity of the working fluid. As a consequence, the relative work fluctuation diverges unless the output work obeys a rather strict scaling condition, which would be very hard to fulfill in practice. Even under this condition, the fluctuations of work and power do not vanish in the infinite system size limit. Large fluctuations of output work thus constitute inseparable and dominant element in performance of the macroscopic heat engines close to a critical point.
We discuss the efficiency of a heat engine operating in a nonequilibrium steady state maintained by two heat reservoirs. Within the general framework of linear irreversible thermodynamics we derive a universal upper bound on the efficiency of the engine operating at arbitrary fixed power. Furthermore, we show that a slight decrease of the power below its maximal value can lead to a significant gain in efficiency. The presented analysis yields the exact expression for this gain and the corresponding upper bound.
Stochastic motion of particles in a highly unstable potential generates a number of diverging trajectories leading to undefined statistical moments of the particle position. This makes experiments challenging and breaks down a standard statistical analysis of unstable mechanical processes and their applications. A newly proposed approach takes advantage of the local characteristics of the most probable particle motion instead of the divergent averages. We experimentally verify its theoretical predictions for a Brownian particle moving near an inflection in a highly unstable cubic optical potential. The most likely position of the particle atypically shifts against the force, despite the trajectories diverging in the opposite direction. The local uncertainty around the most likely position saturates even for strong diffusion and enables well-resolved position detection. Remarkably, the measured particle distribution quickly converges to a quasistationary one with the same atypical shift for different initial particle positions. The demonstrated experimental confirmation of the theoretical predictions approves the utility of local characteristics for highly unstable systems which can be exploited in thermodynamic processes to uncover energetics of unstable systems.