Executing the obligation of strengthened concrete is essential in investigating load exchanges from concrete to the inner reinforcing bar. The bond–displacement conduct and extreme pullout quality for pullout samples are essential information related to the durability of RC structures. The slip in the interface is basically due to a contrast in stresses between concrete and reinforcement. This distinction brings about the start of the split in encompassing concrete. This study examined the simple pullout solid 3D cylinder model strengthened by a reinforced steel bar, considered a line element for bond–slip conduct. The non-linear finite element model utilizing ANSYS software was established to concentrate on the concrete and steel reinforcement bond. Material nonlinearity because of cracking, crushing of concrete, and the steel reinforcing bar’s yielding were investigated. Test results showed that: a prediction model for early-age bond stress–slip relationship between steel bars and concrete was proposed based on modeling, which showed good agreement with test results. The precision of this model is explored by contrasting the finite element numerical analysis and that anticipated from test consequences of pullout examples. Immense homogeneity between the model and test results was found. This study could provide more accurate bond properties for structural analysis and design.