This study verified pollution levels through evaluation of the Sediment Quality Guidelines (SQGs), pollution load index (PLI), and potential ecological risk index (PERI) by analyzing the concentrations of heavy metals in sediments of an urban‒agricultural watershed in the Yeongsan River basin, South Korea. Statistical analyses were performed to determine the relationships between pollution levels and land use, and potential sources of pollution were identified. For spatial distributions, Pb, Zn, Cu, Cd, and Hg concentrations were highest at mid-upstream, but As, Cr, and Ni concentrations were similar at most sites. The polluted sites, which showed the potential toxicity toward benthic organisms in comparison to SQGs, were most frequently observed at mid-upstream. Moreover, PLI and PERI evaluations also confirmed levels of high anthropogenic pollution and the potential ecological risk at mid-upstream. The mid-upstream sites with high heavy metal pollutions showed high correlations with urban land use, which showed the highest distribution, implying a close relationship with anthropogenic impacts such as high population density and industrial complexes. Statistical analyses also confirmed that high heavy metal concentrations in the mid-upstream were closely related to urban land use. These findings suggest that urban areas are highly likely to cause anthropogenic heavy metal pollution in sediments as point or non-point sources such as domestic sewage and industrial wastewater flow into rivers.

The assessment of potential radiation hazards in accumulated sediments in aquatic ecosystems is vital for the management and disposal of sediments. Furthermore, preemptive management of radionuclides in terrestrial ecosystems is critical for marine ecosystem conservation. We analyzed the activity concentrations of natural radionuclides (²²⁶Ra,²³²Th, ²³⁸U, and ⁴⁰K) in the surface sediments of major river watersheds in Korea and evaluated the radiation hazards stemming from these activity concentrations. The mean activity concentrations of ²²⁶Ra and ²³⁸U were lower than the global average, whereas those of ²³²Th and ⁴⁰K were higher. The mean values of radium equivalent activity, external hazard index, and internal hazard index calculated from these activity concentrations did not exceed the recommended maximum values. The mean values of absorbed gamma dose rate in air and annual outdoor effective dose rate (AEDR_out) were higher than the global average by the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) but remarkably lower than the recommended and background values by the International Commission on Radiological Protection (ICRP) and the Korea Institute of Nuclear Safety (KINS). The contribution of ⁴⁰K and ²³²Th to the AEDR_out mean value was predominant. In conclusion, the surface sediments of major river watersheds in Korea are associated with negligible radiation hazards. These findings provide fundamental data for the management and treatment of sediments in terrestrial and marine ecosystems.

This study investigated the accumulation of total phosphorus (TP) and heavy metals (HMs; Pb, Zn, Cu, Cd, Cr, and Ni) in citrus orchard soils in Jeju Island, Korea, identifying potential soil pollution sources using statistical analysis. Anthropogenic HM pollution was evaluated using the geoaccumulation index and enrichment factors, whereas HM bioavailability was assessed via single extraction. TP, Zn, Cu, and Cr concentrations in citrus orchard topsoil were significantly higher than those in forestland soils, indicating their accumulation in the surface layer. Statistical analyses confirmed that elements with high concentrations were closely related to potential pollution sources accumulated on the surface layer of citrus orchards owing to agricultural activities. Particularly, Zn and Cu accumulation was confirmed to originate from intensive compost and pesticide use in citrus orchards. Cu showed the highest contamination and enrichment of all HMs. However, Zn and Cu fractions, determined via an availability assessment, were dominated by acid or complex compounds, indicating that labile Zn and Cu have potential bioavailability for plants. Nevertheless, their fractions accounted for a small proportion (mean < 15%). Therefore, despite the high pollution levels of Zn and Cu, their availabilities were extremely low, indicating a negligible bioavailability in crops and no impact on aquatic ecosystems.