Biochar is considered as a potential substitute for soil organic matter (SOM). Considering the importance of biochar, the present review is based on the different benefits and potential risks of the application of biochar to the soil. Biochar addition to low organic carbon soils can act as a feasible solution to keep soil biologically active for the cycling of different nutrients. The application of biochar could improve soil fertility, increase crop yield, enhance plant growth and microbial abundance, and immobilize different contaminants in the soil. It could also be helpful in carbon sequestration and the return of carbon stock back to the soil in partially combusted form. Due to the large surface area of biochar, which generally depends upon the types of feedstock and pyrolysis conditions, it helps to reduce the leaching of fertilizers from the soil and supplies additional nutrients to growing crops. However, biochar may have some adverse effects due to emissions during the pyrolysis process, but it exerts a positive priming effect (a phenomenon in which subjection to one stimulus positively influences subsequent stimulus) on SOM decomposition, depletion of nutrients (macro- and micro-) via strong adsorption, and impact on soil physicochemical properties. In view of the above importance and limitations, all possible issues related to biochar application should be considered. The review presents extensive detailed information on the sustainable approach for the environmental use of biochar and its limitations.
Method of determination of heavy metals loosely bound compounds in the soil was developed using three separate extractions. The group of loosely bound compounds of metals includes exchangeable, complexed, and specifically adsorbed forms. This method is available, rapid and not expensive. Extraction takes less than 24 h. Sample procedure preparation is simple, and the analysis consists of only three steps, which can be performed simultaneously. The parallel extraction gives reliable and reproducible results and provides a relatively complete idea of the metals mobility in the soil, their availability to plants, migratory capacity, and transformation. •Method is suitable for a wide range of heavy metals and soil types. From the obtained data, the content of loosely bound compounds of heavy metals and the coefficients of metals mobility in the soil can be calculated.•Method is suitable for estimation the microelement supply of uncontaminated soils. The content of elements in the 1 N CH3COONH4 extract characterizes the actual pool of elements, and their content in the 1 N HCl extract defines their potential pool in the soil.•The coefficient of mobility (Km) is calculated to assess the contamination of soil with heavy metals. Estimation criteria of Km for Haplic Chernozem were developed.
1 March 2017 in Journal of Geochemical Exploration
The consequences of heavy metal contamination are progressively degrading soil quality in this modern period of industry. Due to this reason, improvement of the soil quality is necessary. Remediation is a method of removing pollutants from the root zone of plants in order to minimize stress and increase yield of plants grown in it. The use of plants to remove toxins from the soil, such as heavy metals, trace elements, organic chemicals, and radioactive substances, is referred to as bioremediation. Biochar and fly ash techniques are also studied for effectiveness in improving the quality of contaminated soil. This review compiles amelioration technologies and how they are used in the field. It also explains how nanoparticles are becoming a popular method of desalination, as well as how they can be employed in heavy metal phytoremediation.