Metal Fe is one of the phases existing on iron-based catalysts for a high-temperature water gas shift reaction (WGSR), but research on the activity of metal Fe in WGSR is almost not reported. In this work, the density functional theory (DFT) method was used to systematically study the reaction activity and mechanisms of WGSR on metal Fe (110), including the dissociation of H₂O, the transformation of CO and the formation of H₂, as well as the analysis of surface electronic properties. The results show that (1) the direct dissociation of H₂O occurs easily on Fe (110) and the energy barrier is less than 0.9 eV; (2) the generation of CO₂ is difficult and its energy barrier is above 1.8 eV; (3) H migrates easily on the Fe surface and the formation of H₂ also occurs with an energy barrier of 1.47 eV. Combined with the results of Fe₃O₄, it can be concluded that the active phase should be Fe₃O₄ with O vacancy defects, and the iron-rich region plays an important role in promoting the formation of H₂ in WGSR.

The corrosion behavior of X80 steel in a near-neutral soil-simulated solution under various DC stray currents and applied strains was investigated using electrochemical measurements (open circuit potential, linear polarization, and electrochemical impedance spectroscopy) and surface analysis techniques. Our results show that a DC stray current has a substantially greater effect on steel corrosion compared to applied strain. However, strain could slow down the corrosion rate in specific conditions by affecting the composition of corrosion products and the structure of the corrosion scale on the surface of the steel. Although the porosity of the corrosion scale of steel without an applied strain will increase with increasing DC currents, once strain is applied, the corrosion scale will become denser. Furthermore, both DC currents and strain can promote steel pitting, and the number and size of pitting holes will increase significantly with an increase in current densities.

In this work, we demonstrated a novel and low-cost full-range optical coherence tomography (FROCT) method. In comparison with the off-pivot approach, which needs precise control of the deflecting distance and should be adjusted for different situations, our proposed method is more flexible without regulating the system itself. Different from the previous systems reported in the literature, which used a high-cost piezo-driven stage to introduce the phase modulation, our system utilizes a cost-effective voice coil motor for retrieving the complex-valued spectral signal. The complex-valued data, with a twofold increase in the accessible depth range, can be calculated using an algorithm based on the Hilbert transform and Dirac delta function. To confirm the effectivity of our method, both simulation and experiments were performed. In particular, for the in vivo experiment, we presented the FROCT result of a fingernail fold, demonstrating the availability of in vivo imaging. Since the key element of our system is a low-cost voice coil motor, which is flexible and more accessible for most of the clinics, we believe that it has great potential to be a clinical modality in the future.

The aspheric light emitted from a pinhole restrains the reconstruction quality of a digital in-line hologram. Herein, the Fresnel-diffracted spot from the first step converging spherical wave diffracted at a rough circular aperture is collimated and expanded to generate an even plane wave, which is converged again by an objective lens and matching a minimum aperture while the central spot is varying from light to dark. We observed that the collected background hologram is filled with a round spot with high contrast as an ideal spherical wave. The resolution board and biology experimental results demonstrated a distinctively reconstructed image without any image processing in a single exposure. The adjustable field of view and magnification, single exposure, and noncontact make it suitable for an online microscope.