In shape-memory polymers, large strain can be fixed at a low temperature and thereafter recovered at a high temperature. If the shape-memory polymer is held at a high temperature for a long time, the irrecoverable strain can attain a new intermediate shape between the shape under the maximum stress and the primary shape. Irrecoverable strain control can be applied to the fabrication of a shape-memory polymer element with a complex shape in a simple method. In the present study, the influence of the strain-holding conditions on the shape recovery and the irrecoverable strain control in polyurethane shape-memory polymer is investigated by tension test of a film and three-point bending test of a sheet. The higher the shape-holding temperature and the longer the shape-holding time, the higher the irrecoverable strain rate. The equation that expresses the characteristics of the irrecoverable strain control is formulated.

A shape memory composite (SMC) was fabricated with a shape memory alloy (SMA) and a shape memory polymer (SMP), and its two-way bending deformation and recovery force were investigated. The results obtained can be summarized as follows: (1) two kinds of SMA tapes which show the shape memory effect (SME) and superelasticity (SE) were heat-treated to memorize the round shape. The shape-memorized round SMA tapes were arranged facing in the opposite directions and were sandwiched between the SMP sheets. The SMC belt can be fabricated by using the appropriate factors: the number of SMP sheets, the pressing force, the heating temperature and the hold time. (2) The twoway bending deformation with an angle of 56 degrees in the fabricated SMC belt is observed based on the SME and SE of the SMA tapes during heating and cooling. (3) If the SMC belt is heated and cooled by keeping the bent form, the recovery force increases during heating and degreases during cooling based on the two-way properties of the SMC. (4) The development and application of high-functional SMCs are expected by the combination of the SMA and the SMP with various kinds of phase transformation temperatures, volume fractions, configurations and heating-cooling rates.

A shape memory composite (SMC) belt with a TiNi-shape memory alloy (SMA) wire fiber and a polyurethane-shape memory polymer (SMP) sheet matrix is fabricated. The bending actuation characteristics of the belt are investigated by the thermomechanical tests. The results obtained are summarized as follows. (1) Residual deflection close to the maximum deflection is obtained by cooling under constant maximum deflection. The residual deflection disappears by heating under no load. Both the rate of shape fixity and the rate of shape recovery are close to 100%. (2) Recovery force appears by heating under constant residual deflection. The recovery force is 93–94% of the maximum force. The development of high functionality of SMC elements is expected by various combinations of SMAs and SMPs.

This paper presents experimental and modeling results of the effects of thermomechanical couplings occurring in a polyurethane shape memory polymer (SMP) subjected to tension at various strain rates within large strains. The SMP mechanical curves, recorded using a testing machine, and the related temperature changes, measured in a contactless manner using an IR camera, were used to investigate the polymer deformation process at various loading stages. The effects of thermomechanical couplings allowed the determination of the material yield point in the initial loading stage, the investigation of nucleation and development of the strain localization at larger strains and the estimation of the effects of thermoelastic behavior during the unloading process. The obtained stress–strain and thermal characteristics, the results of the dynamic mechanical analysis and estimated values of the shape fixity and shape recovery parameters confirmed that the shape memory polymer ( T _g = 45 °C) is characterized by good mechanical and shape memory properties, as well as high sensitivity to the strain rate. The mechanical response of the SMP subjected to tension was simulated using the finite element method and applying the large strain, two-phase model. Strain localization observed in the experiment was well reproduced in simulations and the temperature spots were correlated with the accumulated viscoplastic deformation of the SMP glassy phase.