In this paper extensive research on the polyurethane shape memory polymer (PU-SMP) is reported, including its structure analysis, our experimental investigation of its thermomechanical properties and its modelling. The influence of the effects of thermomechanical couplings on the SMP behaviour during tension at room temperature is studied using a fast and sensitive infrared camera. It is shown that the thermomechanical behaviour of the SMP significantly depends on the strain rate: at a higher strain rate higher stress and temperature values are obtained. This indicates that an increase of the strain rate leads to activation of different deformation mechanisms at the micro-scale, along with reorientation and alignment of the molecular chains. Furthermore, influence of temperature on the SMP’s mechanical behaviour is studied. It is observed during the loading in a thermal chamber that at the temperature 20 °C below the glass transition temperature ( T _g ) the PU-SMP strengthens about six times compared to the material above T _g but does not exhibit the shape recovery. A finite-strain constitutive model is formulated, where the SMP is described as a two-phase material composed of a hyperelastic rubbery phase and elastic-viscoplastic glassy phase. The volume content of phases is governed by the current temperature. Finally, model predictions are compared with the experimental results.

The presented work is devoted to a new simple method of determination of the energy storage rate (the ratio of the stored energy increment to the plastic work increment) that allows obtaining distribution of this quantity in the area of strain localization. The method is based on the simultaneous measurements of the temperature and displacement distributions on the specimen surface during a tensile deformation. The experimental procedure involves two complementary techniques: i.e. infrared thermography (IRT) and visible light imaging. It has been experimentally shown that during the evolution of plastic strain localization the energy storage rate in some areas of the deformed specimen drops to zero. It can be treated as the plastic instability criterion.