Increasing environmental awareness has boosted interest in sustainable alternatives for binding natural reinforcing fibers in composites. Utilizing lignin, a biorenewable polymer byproduct from several industries, as a component in polymer matrices can lead to the development of more eco-friendly and high-performance composite materials. This research work aimed to investigate the effect of two types of lignin (lignosulfonate and soda lignin) on the properties of hemp fiber-reinforced polypropylene composites for furniture applications. The composites were produced by thermoforming six overlapping layers of nonwoven material. A 20% addition of soda lignin or lignosulfonate (relative to the nonwoven mass) was incorporated between the nonwoven layers made of 80% hemp and 20% polypropylene (PP). The addition of both types of lignin resulted in an increase in the tensile and bending strength of lignin-based composites, as well as a decrease in the absorbed water percentage. Compared to oriented strand board (OSB), lignin-based composites exhibited better properties. Regarding the two types of lignin used, the addition of lignosulfonate resulted in better composite properties than those containing soda lignin. Thermal analysis revealed that the thermal degradation of soda lignin begins long before the melting temperature of polypropylene. This early degradation explains the inferior properties of the composites containing soda lignin compared to those with lignosulfonate.
The use of biomass mixtures as a feedstock in the production of pellets requires optimization of the percentages of the components, since interactions occur during combustion between the components forming the blend (lignin, cellulose, and hemicellulose), affecting characteristics of pellets such as calorific value, ash content, fine fraction content, bulk density, and mechanical durability. Our study focuses on the assessment of the quality of pellets produced from biomass blends generated from pruning seabuckthorn and blackberry mixed with wheat straw. The results of literature data analysis and laboratory research show that wheat straw pellets exhibited the lowest calorific value (15.2 ± 0.2 MJ/Kg) and the highest ash content (5.7 ± 0.18%) while seabuckthorn and blackberry biomass pellets possessed significantly higher calorific value with low ash content. According to the maximization of the mixtures taken in the study, it was proved that the addition of up to 25% wheat straw remaining seabuckthorn biomass provides all the qualitative indicators specified by ENPlus 3 standards. The straw content can be increased up to 35% if 10–20% of blackberry biomass is added to the mixture. The production of pellets from biomass mixtures with an optimized composition, meeting the requirements of EN3Plus standards, will benefit the environment and the agricultural economy by replacing polluting fuels and making optimal use of straw and fruit tree pruning residues.