The recent use of hyperspectral remote sensing imagery has introduced new opportunities for soil organic carbon (SOC) assessment and monitoring. These data enable monitoring of a wide variety of soil properties but pose important methodological challenges. Highly correlated hyperspectral spectral bands can affect the prediction and accuracy as well as the interpretability of the retrieval model. Therefore, the spectral dimension needs to be reduced through a selection of specific spectral bands or regions that are most helpful to describing SOC. This study evaluates the efficiency of visible near-infrared (VNIR) and shortwave near-infrared (SWIR) hyperspectral data to identify the most informative hyperspectral bands responding to SOC content in agricultural soils. Soil samples (111) were collected over an agricultural field in southern Ontario, Canada and analyzed against two hyperspectral datasets: An airborne Nano-Hyperspec imaging sensor with 270 bands (400–1000 nm) and a laboratory hyperspectral dataset (ASD FieldSpec 3) along the 1000–2500 nm range (NIR-SWIR). In parallel, a multimethod modeling approach consisting of random forest, support vector machine, and partial least squares regression models was used to conduct band selections and to assess the validity of the selected bands. The multimethod model resulted in a selection of optimal band or regions over the VNIR and SWIR sensitive to SOC and potentially for mapping. The bands that achieved the highest respective importance values were 711–715, 727, 986–998, and 433–435 nm regions (VNIR); and 2365–2373, 2481–2500, and 2198–2206 nm (NIR-SWIR). Some of these bands are in agreement with the absorption features of SOC reported in the literature, whereas others have not been reported before. Ultimately, the selection of optimal band and regions is of importance for quantification of agricultural SOC and would provide a new framework for creating optimized SOC-specific sensors.

The impacts of tillage practices and crop rotations are fundamental factors influencing changes in the soil carbon, and thus the sustainability of agricultural systems. The objective of this study was to compare soil carbon status and temporal changes in topsoil from different 4 year rotations and tillage treatments (i.e., no-till and conventional tillage). Rotation systems were primarily corn and soy-based and included cereal and alfalfa phases along with red clover cover crops. In 2018, soil samples were collected from a silty-loam topsoil (0–15 cm) from the 36 year long-term experiment site in southern Ontario, Canada. Total carbon (TC) contents of each sample were determined in the laboratory using combustion methods and comparisons were made between treatments using current and archived samples (i.e., 20 year and 9 year change, respectively) for selected crop rotations. Overall, TC concentrations were significantly higher for no-till compared with conventional tillage practices, regardless of the crop rotations employed. With regard to crop rotation, the highest TC concentrations were recorded in corn–corn–oats–barley (CCOB) rotations with red clover cover crop in both cereal phases. TC contents were, in descending order, found in corn–corn–alfalfa–alfalfa (CCAA), corn–corn–soybean–winter wheat (CCSW) with 1 year of seeded red clover, and corn–corn–corn–corn (CCCC). The lowest TC concentrations were observed in the corn–corn–soybean–soybean (CCSS) and corn–corn–oats–barley (CCOB) rotations without use of cover crops, and corn–corn–soybean–winter wheat (CCSW). We found that (i) crop rotation varieties that include two consecutive years of soybean had consistently lower TC concentrations compared with the remaining rotations; (ii) TC for all the investigated plots (no-till and/or tilled) increased over the 9 year and 20 year period; (iii) the no-tilled CCOB rotation with 2 years of cover crop showed the highest increase of TC content over the 20 year change period time; and (iv) interestingly, the no-till continuous corn (CCCC) rotation had higher TC than the soybean–soybean–corn–corn (SSCC) and corn–corn–soybean–winter wheat (CCSW). We concluded that conservation tillage (i.e., no-till) and incorporation of a cover crop into crop rotations had a positive effect in the accumulation of TC topsoil concentrations and could be suitable management practices to promote soil fertility and sustainability in our agricultural soils.

Warm season perennial C4 grasses (WSGs), switchgrass (Panicum virgatum L.) and miscanthus species (Miscanthus spp.), have been reported to positively influence short-term (15–20 years) soil organic carbon (SOC). In this study, the DayCent model was used to predict changes in long-term SOC stocks under WSGs for moderate (Representative Concentration Pathway (RCP) 4.5) and high (RCP 8.5) warming climate change scenarios in southern Ontario, Canada, and to determine how long the enhanced SOC stock will last when WSGs are converted back to annual crop rotation. The model predicted that a consistent corn–corn–soybean–winter wheat (CCSW) rotation prevented SOC from depletion over the 21st century. Under WSGs, the model predicted high rates of SOC sequestration during the first 20–30 years which then tended to stabilize after 50–60 years. However, the rate of SOC sequestration over 90 years for RCP 4.5 was 0.26 and 0.94 Mg C ha⁻¹ yr⁻¹ for switchgrass and miscanthus, respectively. If 40-year stands of WSGs are converted back to CCSW, the model predicted SOC decline to the previous level in 40–50 years. DayCent predicted that under RCP 8.5 scenario in the second half of the 21st century and in the future, there will be a reduction in SOC stocks, especially under miscanthus stands.

Total nitrogen (TN) is a critical nutrient for plant growth, and its monitoring in agricultural soil is vital for farm managers. Traditional methods of estimating soil TN levels involve laborious and costly chemical analyses, especially when applied to large areas with multiple sampling points. Remote sensing offers a promising alternative for identifying, tracking, and mapping soil TN levels at various scales, including the field, landscape, and regional levels. Spaceborne hyperspectral sensing has shown effectiveness in reflecting soil TN levels. This study evaluates the efficiency of spectral reflectance at visible near-infrared (VNIR) and shortwave near-infrared (SWIR) regions to identify the most informative hyperspectral bands responding to the TN content in agricultural soil. In this context, we used PRISMA (PRecursore IperSpettrale della Missione Applicativa) hyperspectral imagery with ensemble learning modeling to identify N-specific absorption features. This ensemble consisted of three multivariate regression techniques, partial least square (PLSR), support vector regression (SVR), and Gaussian process regression (GPR) learners. The soil TN data (n = 803) were analyzed against a hyperspectral PRISMA imagery to perform spectral band selection. The 803 sampled data points were derived from open-access soil property and nutrient maps for Africa at a 30 m resolution over a bare agricultural field in southern Morocco. The ensemble learning strategy identified several bands in the SWIR in the regions of 900–1300 nm and 1900–2200 nm. The models achieved coefficient-of-determination values ranging from 0.63 to 0.73 and root-mean-square error values of 0.14 g/kg for PLSR, 0.11 g/kg for SVR, and 0.12 g/kg for GPR, which had been boosted to an R² of 0.84, an RMSE of 0.08 g/kg, and an RPD of 2.53 by the ensemble, demonstrating the model’s accuracy in predicting the soil TN content. These results underscore the potential for using spaceborne hyperspectral imagery for soil TN estimation, enabling the development of decision-support tools for variable-rate fertilization and advancing our understanding of soil spectral responses for improved soil management.

Globally, agricultural soils are being evaluated for their role in climate change regulation as a potential sink for atmospheric carbon dioxide (CO₂) through sequestration of organic carbon as soil organic matter. Scientists and policy analysts increasingly seek to develop programs and policies which recognize the importance of mitigation of climate change and insurance of ecological sustainability when managing agricultural soils. In response, many countries are exploring options to develop local land-use carbon inventories to better understand the flow of carbon in agriculture to estimate its contribution to greenhouse gas (GHG) reporting. For instance, the Canadian province of Ontario does not currently have its own GHG inventory and relies on the Canada’s National Inventory Report (NIR). To address this, the province explored options to develop its own land-use carbon inventory to better understand the carbon resource in agricultural soils. As part of this undertaking, a gap analysis was conducted to identify the critical information gaps and limitations in estimating soil organic carbon (SOC) monitoring to develop a land-use carbon inventory (LUCI) for the cropland sector in Ontario. We conducted a review of analytical and modeling methods used to quantify GHG emissions and reporting for the cropland sectors in Canada, and compared them with the methods used in seven other countries (i.e., France, United Kingdom; Germany; United States of America, Australia, New Zealand, and Japan). From this comparison, four target areas of research were identified to consider in the development of a cropland sector LUCI in Ontario. First, there needs to be a refinement of the modelling approach used for SOC accounting. The Century model, which is used for Ontario’s cropland sector, can benefit from updates to the crop growth model and from the inclusion of manure management and other amendments. Secondly, a raster-based spatially explicit modelling approach is recommended as an alternative to using polygon-based inputs for soil data and census information for land management. This approach can leverage readily available Earth Observation (EO) data (e.g., remote sensing maps, digital soil maps). Thirdly, the contributions from soil erosion need to be included in inventory estimates of SOC emissions and removals from cropland. Fourth, establishment of an extensive network of long-term experimental sites to calibrate and validate the SOC models (i.e., CENTURY) is required. This can be done by putting in place a ground-truth program, through farmer-led research initiatives and collaboration, to deal with uncertainties due to spatial variability and regional climates. This approach would provide opportunities for farmers to collaborate on data collection by keeping detailed records of their cropping and soil management practices, and crop yields.