Increasing the concentration of oxygen vacancies in ceria-based materials to solve the bottleneck of their applications in various fields has always been a research hotspot. In this paper, ceria-based cerium–oxygen–sulfur (Ce-O-S) composites that were composed of CeO2, Ce4O4S3, and Ce2(SO4)3 were synthesized by a precipitation method. The compositional, structural, morphological, and light response characteristics of prepared Ce-O-S composites were investigated by various characterization techniques. The molar ratio of oxygen vacancies to lattice oxygen can reach a maximum of 1.83 with Ce-O-S composites. The band gap values of the Ce-O-S composites were less than 3.00 eV, and the minimum value was 2.89 eV (at pH 12), which successfully extended the light response range from the ultraviolet light region to the short-wave blue light region. The remarkable light response performance of Ce-O-S composites can be mainly attributed to the high proportion of oxygen vacancy. Moreover, the higher proportion of oxygen vacancies can be attributed to the doping of Ce (+3) and S (−2) in the lattice of CeO2, and the synergistic effect of CeO2, Ce4O4S3, and Ce2(SO4)3. Moreover, the ceria-based Ce-O-S composites with rich oxygen vacancy in this research can be applied in light blocking, photocatalysis, and other related fields.
Porous 316L stainless steel has a low density and high specific surface area, and is easy to process due to the large number of pores within it, making it ideal for applications such as piping in the chemical and food industries, as a medical tool, or as a fuel cell pole plate material. Nitriding treatment can further improve the hardness and strength of porous stainless steel. In this paper, a method combining vacuum sintering and nitriding treatment was proposed, i.e., 316L stainless steel powder was used as the raw material, and porous 316L was sintered in a vacuum tube furnace, in which the porous stainless steel was nitrided with nitrogen gas during the cooling process. In the research process, thermodynamic calculation and differential thermal analysis were used to determine the optimum nitriding temperature range of 700 °C~850 °C and nitriding pressure of 0.4 MPa~0.8 MPa. With the increase in nitriding temperature and pressure, the nitrogen content in the sample increased, and the nitrogen content of porous 316L stainless steel after nitriding was 0.03%~0.86%. The results show that nitrogen exists exclusively in solid solution at nitriding temperatures of 700 °C and 750 °C. At nitriding temperatures of 800 °C and 850 °C, the nitrogen existed in both solid solution and chromium nitride (CrN), and the Vickers hardness at 0.08 MPa and 850 °C was 135 HV, which was 2.82 times higher than that before nitriding. The compressive strength of the specimens was maximum at a nitriding pressure of 0.04 MPa and 850 °C. The corrosion resistance of the specimens is optimized when the nitriding pressure is 0.04 MPa and the temperature is 800 °C.