In order to study what the effect of superplasticizers on the setting time, fluidity and compressive strength of calcium sulfoaluminate cement (CSA) a naphthalene-based superplasticizer (BNS) and a polycarboxylic acid superplasticizer (PC) were selected to interact with CSA pastes and ye’elimite, respectively. X-ray diffraction (XRD), thermogravimetric (TG) analysis and scanning electron microscopy (SEM) analytical methods were used to investigate the class, amount and microstructure of the CSA pastes and ye’elimite pastes hydration products under the effect of the superplasticizers. The results showed that the addition of BNS can promote ettringite generation and thus improve the early compressive strength. As the addition of BNS increased from 0.8 wt% to 2.0 wt%, the initial setting time was prolonged 10 min, the final setting time was prolonged 7 min, the 5 min fluidity was improved from no fluidity to 220 mm. However, as the addition of PC increased from 0.08 wt% to 0.20 wt%, the setting time of the PC just changed within 3 min; the 5 min fluidity increased from 110 mm to 195 mm and no 15 min fluidity at all was observed. AS seen by SEM, it can be stated that generated ettringite under the addition of PC was layered and lacking bonding, and its morphology changed from rod-like to flake-like, leading to a decrease in early compressive strength.
The application of brick–concrete recycled aggregates can alleviate the problem of increasing construction waste and increasing scarcity of natural aggregates. The different moisture condition of coarse aggregates can significantly affect the performance of brick–concrete recycled aggregate concrete. In this paper, the additional water quantity of dry and air-dried brick–concrete recycled coarse aggregate concrete was determined. Additionally, the fluidity, rheological parameters, autogenous shrinkage, strength and chloride ion penetration resistance were tested, and compared with saturated surface dry recycled brick–concrete coarse aggregate concrete and natural aggregate concrete. The results showed that the slump of concrete was increased, whereas the plastic viscosity, static and dynamic yield stress were decreased by adding additional water or using saturated surface dry coarse aggregate. Compared with the dry and saturated surface dry state, the air-dried recycled coarse aggregate concrete has the smallest 28 days autogenous shrinkage value, higher compressive strength and splitting tensile strength, and less adverse effects on chloride permeability. It is most beneficial to the performance and economy of concrete to adopt the air-dried state when the brick–concrete recycled coarse aggregate is applied in engineering.
The properties of concrete can be significantly affected by sodium gluconate (SG) at very small dosages. In this paper, the effects of SG on the fluidity, setting time, heat of hydration, and strength of ultra-high-performance concrete (UHPC) were studied. The results show that (1) in the plastic stage, SG inhibited the formation of early ettringite (AFt) and delayed the hydration of tricalcium silicate (C3S) and dicalcium silicate (C2S). SG increased the initial fluidity of UHPC without decreasing within 1 h. When the SG dosage was ≥0.06%, the slumps at 30 min and 60 min increased slightly. (2) In the setting hardening stage, the addition of SG inhibited the formation of calcium hydroxide (CH), which significantly extended the setting time of UHPC. When the dosage of SG was 0.15%, the initial and final setting times were 5.0 times and 4.5 times that of the blank group, respectively. SG had no obvious effect on the hydration rate of cement in the accelerated period, but the peak hydration temperature of UHPC was increased when the SG dosage was 0.03~0.12%. (3) In the strength development stage, the 1 d and 3 d strength of UHPC decreased significantly with the increase in the SG dosage. However, SG could promote the formation of AFt at the pores and aggregate interface in the later stage, reduce the porosity of cementite, and improve the compressive strength of UHPC in 28 d, 60 d, and 90 d. When the SG dosage was 0.12%, the 90d strength increased by 13%.
The influence of sodium gluconate (SG) on the adsorption of polynaphthalene sulfonate (PNS) superplasticiser on the surface of particles was investigated using cement and fly ash pastes. Below the saturated PNS dosage, SG reduces the fluidity loss of the two pastes and the amount of PNS adsorbed on the particle surface. The similarity of this behaviour for the two pastes indicates that inhibition of cement hydration is not the sole reason for SG reduction of fluidity loss of cement paste with PNS. X-ray photoelectron spectroscopy data show competing adsorption forces between SG and polar groups of PNS on the active points of the cement particle surface. This reduces the transformation rate from a caudal style to either a ring or horizontal PNS adsorptive style, as confirmed by dynamic adsorptive models. These are important mechanisms of SG reduction in the fluidity loss of cement pastes with PNS.
Pervious planting concrete (PPC) is in line with the concept of ecological environmental protection. However, due to its own porous structure, it is difficult to obtain excellent mechanical properties and water permeability at the same time, which hinders its promotion and application. In this paper, natural gravel (NG), ordinary Portland cement (OPC), polyvinyl alcohol latex powder (PVAP) and polycarboxylate superplasticizer (PS) were used to prepare the PPC, and its mechanical properties and water permeability were studied. Three kinds of plants were planted in the PPC and their planting properties were studied. At the same time, the effect of Bacillus on the planting properties was studied. The results show that when the water–binder ratio (W/B) was 0.28 and the PVAP content was 0.8%, both the mechanical properties and water permeability of the PPC were optimal. The compressive strength and permeability coefficient were 14.2 MPa and 14.48 mm/s, respectively. The mechanical properties and water permeability of PPC prepared with 10~20 mm NG were better than those prepared with 5~10 mm NG. Among the three plants, the germination rate and growth of Elymus dahuricus Turcz (EDT) were the best. The incorporation of Bacillus can optimize its planting properties and promote the effective combination between plants and the PPC substrate.