We propose a new facile electrochemical sensing platform for determination of urea, based on a glassy carbon electrode (GCE) modified with nickel cobalt oxide (NiCo₂O₄) nanoneedles.

A facile and efficient electrochemical sensing platform has been successfully exploited for the first time for the determination of lactic acid using a nickel oxide (NiO) nanoparticle-modified glassy carbon electrode (GCE).

Using the hydrothermal method followed by the SILAR method, synthesis of CuO/Ag₂WO₄-5 photocathode that is effective for PEC water splitting when illuminated by solar light is provided.

In this study, we synthesized hybrid systems based on manganese oxide@zinc oxide (Mn₃O₄@ZnO), using sol gel and hydrothermal methods. The hybrid materials exhibited hierarchical morphologies and structures characterized by the hexagonal phase of ZnO and the tetragonal phase of Mn₃O₄. The hybrid materials were tested for degradation of methylene blue (MB), methyl orange (MO), and malachite green (MG) under ultraviolet (UV) light illumination. The aim of this work was to observe the effect of various amounts of Mn₃O₄ in enhancing the photocatalytic properties of ZnO-based hybrid structures towards the degradation of MB, MO and MG. The ZnO photocatalyst showed better performance with an increasing amount of Mn₃O₄, and the degradation efficiency for the hybrid material containing the maximum amount of Mn₃O₄ was found to be 94.59%, 89.99%, and 97.40% for MB, MO and MG, respectively. The improvement in the performance of hybrid materials can be attributed to the high charge separation rate of electron-hole pairs, the co-catalytic role, the large number of catalytic sites, and the synergy for the production of high quantities of oxidizing radicals. The performance obtained from the various Mn₃O₄@ZnO hybrid materials suggest that Mn₃O₄ can be considered an effective co-catalyst for a wide range of photocatalytic materials such as titanium dioxide, tin oxide, and carbon-based materials, in developing practical hybrid photocatalysts for the degradation of dyes and for wastewater treatment.

An electrocatalyst based on a nickel iron layered double hydroxide functionalized Co₃O₄ core shell structure.

Designing a facile and low-cost methodology to fabricate earth-abundant catalysts is very much needed for a wide range of applications. Herein, a simple and straightforward approach was developed to tune the electronic properties of cobalt oxide nanostructures by doping them with nickel and then using them to catalyze the oxygen evolution reaction (OER) in an aqueous solution of 1.0 M KOH. The addition of a nickel impurity improved the conductivity of the cobalt oxide, and further increased its activity towards the OER. Analytical techniques such as scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and powder X-ray diffraction (XRD) were used to investigate, respectively, the morphology, composition and crystalline structure of the materials used. The nickel-doped cobalt oxide material showed randomly oriented nanowires and a high density of nanoparticles, exhibited the cubic phase, and contained cobalt, nickel and oxygen as its main elements. The nickel-doped cobalt oxide also yielded a Tafel slope of 82 mV dec⁻¹ and required an overpotential of 300 mV to reach a current density of 10 mA cm⁻². As an OER catalyst, it was shown to be durable for 40 h. Electrochemical impedance spectroscopy (EIS) analysis showed a low charge-transfer resistance of 177.5 ohms for the nickel-doped cobalt oxide, which provided a further example of its excellent OER performance. These results taken together indicated that nickel doping of cobalt oxide can be accomplished via a facile approach and that the product of this doping can be used for energy and environmental applications.