Herein, tetracycline adsorption employing magnetic chitosan (CS·Fe₃O₄) as the adsorbent is reported. The magnetic adsorbent was synthesized by the co-precipitation method and characterized through FTIR, XRD, SEM, and VSM analyses. The experimental data showed that the highest maximum adsorption capacity was reached at pH 7.0 (211.21 mg g⁻¹). The efficiency of the magnetic adsorbent in tetracycline removal was dependent on the pH, initial concentration of adsorbate, and the adsorbent dosage. Additionally, the ionic strength showed a significant effect on the process. The equilibrium and kinetics studies demonstrate that Sips and Elovich models showed the best adjustment for experimental data, suggesting that the adsorption occurs in a heterogeneous surface and predominantly by chemical mechanisms. The experimental results suggest that tetracycline adsorption is mainly governed by the hydrogen bonds and cation–π interactions due to its pH dependence as well as the enhancement in the removal efficiency with the magnetite incorporation on the chitosan surface, respectively. Thermodynamic parameters indicate a spontaneous and exothermic process. Finally, magnetic chitosan proves to be efficient in TC removal even after several adsorption/desorption cycles.

Silica nanoparticles have been widely explored in biomedical applications, mainly related to drug delivery and cancer treatment. These nanoparticles have excellent properties, high biocompatibility, chemical and thermal stability, and ease of functionalization. Moreover, silica is used to coat magnetic nanoparticles protecting against acid leaching and aggregation as well as increasing cytocompatibility. This review reports the recent advances of silica-based magnetic nanoparticles focusing on drug delivery, drug target systems, and their use in magnetohyperthermia and magnetic resonance imaging. Notwithstanding, the application in other biomedical fields is also reported and discussed. Finally, this work provides an overview of the challenges and perspectives related to the use of silica-based magnetic nanoparticles in the biomedical field.

This paper reports a high efficiency uptake of captopril (CPT), employing magnetic graphene oxide (MGO) as the adsorbent. The graphene oxide (GO) was produced through an oxidation and exfoliation method, and the magnetization technique by the co-precipitation method. The nanomaterials were characterized by FTIR, XRD, SEM, Raman, and VSM analysis. The optimal condition was reached by employing GO·Fe₃O₄ at pH 3.0 (50 mg of adsorbent and 50 mg L⁻¹ of CPT), presenting values of removal percentage and maximum adsorption capacity of 99.43% and 100.41 mg g⁻¹, respectively. The CPT adsorption was dependent on adsorbent dosage, initial concentration of adsorbate, pH, and ionic strength. Sips and Elovich models showed the best adjustment for experimental data, suggesting that adsorption occurs in a heterogeneous surface. Thermodynamic parameters reveal a favorable, exothermic, involving a chemisorption process. The magnetic carbon nanomaterial exhibited a high efficiency after five adsorption/desorption cycles. Finally, the GO·Fe₃O₄ showed an excellent performance in CPT removal, allowing future application in waste management.

Among biotic and abiotic stresses, the most restrictive for plant distribution is salt stress, where different concentrations might exert harmful effects on seed germination. Recently, nanomaterials were used successfully to mitigate these stresses, indicating that plants may be able to develop normally in adverse conditions. The aim of this study was to examine the effects of graphene oxide (GO) on the germination of Persian clover seedlings under salt stress conditions. Following sown on substrate paper, seeds were tested after exposure to different concentrations of graphene oxide (0, 125, 250, or 500 mg L^-1 GO), sodium chloride (0; -0.1; -0.2; -0.3, or -0.4 MPa NaCl) and/or GO + salt concomitantly, and then stored for 7 days in a germination chamber at 20°C in the presence of light. Seed germination and growth parameters of seedlings were determined. Graphene oxide demonstrated protective effect against salt stress as evident by no marked adverse effects on seed germination where GO blocked the salt-induced reduction in germination. The results obtained provide references for the safe application of nanomaterials and emphasize the significance of GO as a promising material for reducing the toxicity of salts in agriculture.